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Cited by 350

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Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

Open access
Cheng, Qian, Li, Aijun, Li, Na, Li, Shuang, Zangiabadi, Amirali, Li, Tai-De, Huang, Wenlong, Li, Alex Ceng, Jin, Tianwei, Song, Qingquan, Xu, Weiheng, Ni, Nan, Zhai, Haowei, Dontigny, Martin, Zaghib, Karim, Chuan, Xiuyun, Su, Dong, Yan, Kai, Yang, Yuan·2019·Joule

Abstract

Summary Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm−2. In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.

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Metadata

Authors
Cheng, Q., Li, A., Li, N., Li, S., Zangiabadi, A., Li, T.-D., Huang, W., Li, A. C., Jin, T., Song, Q., Xu, W., Ni, N., Zhai, H., Dontigny, M., Zaghib, K., Chuan, X., Su, D., Yan, K., & Yang, Y.
Venue
Joule
Publisher
Elsevier BV
Published
2019-06
Volume
3
Issue
6
Pages
1510-1522
ISSN
2542-4351 (ISSN-L)
OpenAlex
W2938899632
Cited by
350
References
1
FWCI
15.07
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating. https://app.cochat.ai/papers/10.1016/j.joule.2019.03.022
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Cheng, Q., Li, A., Li, N., Li, S., Zangiabadi, A., Li, T.-D., Huang, W., Li, A. C., Jin, T., Song, Q., Xu, W., Ni, N., Zhai, H., Dontigny, M., Zaghib, K., Chuan, X., Su, D., Yan, K., & Yang, Y. (2019). Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating. Joule. https://doi.org/10.1016/j.joule.2019.03.022

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.