The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Designer Anion Enabling Solid-State Lithium-Sulfur Batteries
Open accessAbstract
Summary With an extremely high theoretical energy density, solid-state lithium-sulfur (Li-S) batteries (SSLSBs) are emerging as one of the most feasible chemistries; however, their energy efficiency and long-term cyclability are severely hampered by the lithium metal (Li°) dendrite formation during repeated discharge/charge cycles and the shuttling of aggressive polysulfide intermediates between two electrodes. Herein, we report (difluoromethanesulfonyl) (trifluoromethanesulfonyl)imide anion [N(SO2CF2H)(SO2CF3)]−, hereafter DFTFSI−, as a designer anion for high-performance polymer-based SSLSBs. In contrast to the widely used bis(trifluoromethanesulfonyl)imide anion [N(SO2CF3)2]− (TFSI−), DFTFSI-based SSLSBs provide superior interfacial stability against Li°, extremely high discharge and areal capacities, very high Coulombic efficiency, and long-term cyclability, surpassing the reported literature values, in terms of gravimetric energy density. This work opens a new door for accelerating the practical deployment of SSLSBs in the future.
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Cites
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
High rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Cited by
Interface engineering toward stable lithium–sulfur batteries
Guo, Y., Niu, Q., Pei, F., Wang, Q., Zhang, Y., Du, L., Zhang, Y., Zhang, Y., Zhang, Y., Fan, L., et al. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04183b · Cited by 322
Metadata
- Authors
- Zhang, H., Oteo, U., Judez, X., Eshetu, G. G., Martinez-Ibañez, M., Carrasco, J., Li, C., & Armand, M.
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2019-07
- Volume
- 3
- Issue
- 7
- Pages
- 1689-1702
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W2946604523
- Cited by
- 158
- References
- 3
- FWCI
- 6.96
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Zhang, H., Oteo, U., Judez, X., Eshetu, G. G., Martinez-Ibañez, M., Carrasco, J., Li, C., & Armand, M. (2019). Designer Anion Enabling Solid-State Lithium-Sulfur Batteries. Joule. https://doi.org/10.1016/j.joule.2019.05.003
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