The DOI matches its Crossref record; 69 of the 69 references it cites were found in a registry or an index.
Li-free Cathode Materials for High Energy Density Lithium Batteries
Open accessAbstract
Conversion-type cathode materials, such as transition metal halides, chalcogenides, and oxides, demonstrate high operational voltages and high specific capacities, offering high energy densities for rechargeable lithium-metal batteries. In this review, a series of low-cost, environmentally benign, and high energy density Li-free cathode materials are selected based on thermodynamic calculations. Coupled with Li/C anodes, these cathodes (e.g., S, FeF3, CuF2, FeS2, and MnO2) have the potential to offer energy densities of 1,000–1,600 Wh kg−1 and 1,500–2,200 Wh L−1 at the cell level. Their main challenges, including capacity fading, high voltage hysteresis, large volume change, and parasitic reactions with electrolytes, are discussed. Strategies to circumvent these issues based on the state-of-the-art technologies are summarized. It seems that all of these challenges are able to be solved. We believe that with the development of practical Li-metal-based anodes and solid-state electrolytes, conversion-type cathodes have a promising future for the next-generation high energy density energy storage devices.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., & Tarascon, J.-M. (2000) · Nature · doi:10.1038/35035045 · Cited by 8,041
Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries
Padhi, A. K., Nanjundaswamy, K. S., & Goodenough, J. B. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837571 · Cited by 7,933
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
Cheng, X.-B., Zhang, R., Zhao, C.-Z., & Zhang, Q. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00115 · Cited by 6,197
Nanomaterials for Rechargeable Lithium Batteries
Bruce, P. G., Scrosati, B., & Tarascon, J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702505 · Cited by 5,886
Promise and reality of post-lithium-ion batteries with high energy densities
Choi, J. W., & Aurbach, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.13 · Cited by 5,110
Lithium battery chemistries enabled by solid-state electrolytes
Manthiram, A., Yu, X., & Wang, S. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.103 · Cited by 4,689
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
Mizushima, K., Jones, P. C., Wiseman, P. J., & Goodenough, J. B. (1980) · Materials Research Bulletin · doi:10.1016/0025-5408(80)90012-4 · Cited by 3,856
High-power all-solid-state batteries using sulfide superionic conductors
Kato, Y., Hori, S., Saito, T., Suzuki, K., Hirayama, M., Mitsui, A., Yonemura, M., Iba, H., & Kanno, R. (2016) · Nature Energy · doi:10.1038/nenergy.2016.30 · Cited by 3,517
High rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Cited by
A non-academic perspective on the future of lithium-based batteries
Frith, J. T., Lacey, M. J., & Ulissi, U. (2023) · Nature Communications · doi:10.1038/s41467-023-35933-2 · Cited by 820
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
Emerging Indoor Photovoltaic Technologies for Sustainable Internet of Things
Pecunia, V., Occhipinti, L. G., & Hoye, R. L. Z. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100698 · Cited by 322
A new cyclic carbonate enables high power/ low temperature lithium-ion batteries
Qian, Y., Chu, Y., Zheng, Z., Shadike, Z., Han, B., Xiang, S., Kang, Y., Hu, S., Cao, C., Zhong, L., et al. (2022) · Energy Storage Materials · doi:10.1016/j.ensm.2021.11.029 · Cited by 74
Metadata
- Authors
- Wang, L., Wu, Z., Zou, J., Gao, P., Niu, X., Li, H., & Chen, L.
- Venue
- Joule
- Publisher
- Elsevier BV
- Published
- 2019-09
- Volume
- 3
- Issue
- 9
- Pages
- 2086-2102
- ISSN
- 2542-4351 (ISSN-L)
- OpenAlex
- W2968167659
- Cited by
- 391
- References
- 69
- FWCI
- 14.98
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Li-free Cathode Materials for High Energy Density Lithium Batteries. https://app.cochat.ai/papers/10.1016/j.joule.2019.07.011
- The paper
- Wang, L., Wu, Z., Zou, J., Gao, P., Niu, X., Li, H., & Chen, L. (2019). Li-free Cathode Materials for High Energy Density Lithium Batteries. Joule. https://doi.org/10.1016/j.joule.2019.07.011
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
