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LiBOB: Is it an alternative salt for lithium ion chemistry?
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“To combine the good ionic conductivity of LiBF 4 and decent SEI formation capability from LiBOB, a LiBF 4 :LiBOB (9:1, molar ratio) dual-salt system was developed by Xu et al. [99,102], in PC/EC/EMC ternary solvent the Li-LiFePO 4 (LFP) cell showed enhanced cyclic performance in a wide-temperature range from -50 to 90 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [102]
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“al, lithium bis(oxalato) borate (LiBOB) was regarded as the most promising alternative as electrolyte for solid lithium-ion batteries [4].”
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“…as the low solubility and low conductivity levels of lithium bis(oxalato) borate (LiBOB) in carbonate solvents (0.8 mol L −1 and 8–9 mS cm −1 ) [21, 22], the high degree of danger posed by lithium perchlorate (LiClO 4 ), the toxicity of lithium hexafluoroarsenate (LiAsF 6 ), and the corrosion of…”
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“This can be attributed to impurities in the LiBOB salt [53], cathode surface-dependent chemical reactivity [53, 54], not detectable via electrochemical methods [55, 56] and/or via enhanced reduction of BOB - on anodes side, leading to higher irreversible capacity loss (Figure 4c).”
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“LiBOB is not only a potential salt for Li-ion batteries but also thermally more stable and environmentally benign because the hydrolytic decomposition products are non-toxic and corrosion resistant [27].”
BackgroundPhysico-Chemical and Electrochemical Properties of Lithium Bis(Oxalate)Borate Solutions in Sulfolane
Sheina, L. V., Ivanov, A. L., Karaseva, E., & Kolosnitsyn, V. (2021) · Russian journal of electrochemistry · doi:10.1134/s1023193521120065 · Cited by 2
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“The differential capacity analysis of the first cycle shows a distinct reduction peak at ca. 1.3 V versus Na + /Na, which has been ascribed to the decomposition of NaDFOB [39] and/or to the reduction of impurities, namely oxalate esters (Figure 1a) [40].”
InfluentialOuld, D. M. C., Ruff, Z., Penrod, M. E., Didwal, P. N., Weiss, T., Mylrea, K., Smith, H., Bond, A. D., Weatherup, R., Grey, C. P., et al. (2025) · Chemistry · doi:10.1002/chem.202502653 · Cited by 1
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Li, S.-Y., Zhao, D.-N., & Chen, R. (2016) · doi:10.2991/emcpe-16.2016.71 · Cited by 1
“[6] Xu K, Zhang S S, and Lee U, et al.”
BackgroundThe research progress of single-ion conducting polymer lithium borate salts
Yang, H.-Y., Ding, G.-L., Duan, Y.-L., Liu, Z.-H., Zhang, J., Cui, G., Qin, B.-S., & Yao, J.-H. (2014) · doi:10.1360/n032014-00058 · Cited by 1
Zhou, H.-M., Geng, W.-J., & Li, J. (2017) · Journal of Central South University · doi:10.1007/s11771-017-3503-z
Fluorine‐Free Strategies for Sustainable Batteries
Zhao, W., Lai, Z.-Y., Li, S., Zhao, Y., Zeng, Y., & Chen, Z. (2026) · ChemSusChem · doi:10.1002/cssc.71020
Tailoring Electrolyte Chemistry Through Precise Organic Synthesis for Lithium Metal Batteries
Chen, J.-Z., Wu, H.-Y., Li, S., Sun, Y.-H., Chang, C., Liu, S.-W., Chee, P.-S., Elshahawy, A. M., Makhlouf, S. A., & Guan, C. (2026) · Advanced Energy Materials · doi:10.1002/aenm.71447
Sidharthan, A. S., Hainthaler, A., Neumann, C., Turchanin, A., & Balducci, A. (2026) · Communications Materials · doi:10.1038/s43246-026-01310-x
Sulfone‐Based Low Fluorine Electrolytes for High‐Voltage Cobalt‐Free Cathodes
Klein, M. J., König, T., Pahari, D., Bianchini, M., & Balducci, A. (2026) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202500494
“Since borate-based salts such as LiBOB have only limited solubility in the carbonate-based solvents used in LIBs, according to publications, the solubility of LiDFOB in EiPS was initially investigated and compared to the solubility in propylene carbonate (PC) [9, 36].”
Mardi, S., Tronde, E., & Hernández, G. (2026) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202500390
Investigation of Si/C-based anodes for Li-Ion batteries
Dölle, J. (2014) · DepositOnce · doi:10.14279/depositonce-4229 · Cited by 1
Metadata
- Authors
- Xu, K., Zhang, S. S., Lee, U., Allen, J. L., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Xu, Kang
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2005-08
- Volume
- 146
- Issue
- 1-2
- Pages
- 79-85
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2079221214
- Cited by
- 203
- References
- 0
- Citations by year
- 2026: 9 · 2025: 16 · 2024: 14 · 2023: 9 · 2022: 15 · 2021: 10 · 2020: 7 · 2019: 7 · 2018: 15 · 2017: 13 · 2016: 9 · 2015: 17 · 2014: 15 · 2013: 6 · 2012: 8
- FWCI
- 5.07
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Keywords
- LiBOB, lithium-ion batteries, electrolyte salts, metal oxide cathodes, electrochemistry, salt impurities, battery safety
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