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Surface structural disordering in graphite upon lithium intercalation/deintercalation
Open accessAbstract
We report on the origin of the surface structural disordering in graphite anodes induced by lithium intercalation and deintercalation processes. Average Raman spectra of graphitic anodes reveal that cycling at potentials that correspond to low lithium concentrations in Lix C( 0≤ x 0.33) are present. Electrochemical impedance spectra show larger interfacial impedance for the electrodes that were fully delithiated during cycling as compared to electrodes that were cycled at lower potentials (U < 0.15 V vs. Li/Li + ). Steep Li
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Cites
Ageing mechanisms in lithium-ion batteries
Vetter, J., Novák, P., Wagner, M. R., Veit, C., Möller, K.-C., Besenhard, J. O., Winter, M., Wohlfahrt-Mehrens, M., Vogler, C., & Hammouche, A. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.01.006 · Cited by 3,987
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Nonlinear aging of cylindrical lithium-ion cells linked to heterogeneous compression
Bach, T. C., Schuster, S. F., Fleder, E., Müller, J., Brand, M. J., Lorrmann, H., Jossen, A., & Sextl, G. (2016) · Journal of Energy Storage · doi:10.1016/j.est.2016.01.003 · Cited by 296
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Effects of inhomogeneities - nanoscale to mesoscale - on the durability of Li-Ion batteries
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de Hoog, J., Timmermans, J.-M., Ioan-Stroe, D., Swierczynski, M., Jaguemont, J., Goutam, S., Omar, N., Van Mierlo, J., & Van Den Bossche, P. (2017) · Applied Energy · doi:10.1016/j.apenergy.2017.05.018 · Cited by 254
Metadata
- Authors
- Sethuraman, V. A., Hardwick, L. J., Srinivasan, V., & Kostecki, R.
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2010-06-01
- Volume
- 195
- Issue
- 11
- Pages
- 3655-3660
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2136547252
- Cited by
- 344
- References
- 1
- FWCI
- 7.39
- Type
- journal article
- Language
- en
- Open access
- green
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- Sethuraman, V. A., Hardwick, L. J., Srinivasan, V., & Kostecki, R. (2010). Surface structural disordering in graphite upon lithium intercalation/deintercalation. Journal of Power Sources. https://doi.org/10.1016/j.jpowsour.2009.12.034
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