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On the origin of the capacity fading for aluminium negative electrodes in Li-ion batteries
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Pure aluminum anode capacity fading is caused by structural damage from excessive volume changes during charge-discharge, leading to crack nucleation and pulverization and loss of electrical contact.
“The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
From Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication (2024) · cites this paper as [10]
Pure aluminum anode capacity fading is caused by loss of lithium due to diffusion into the bulk or formation of stable AlLi phases.
“The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
From Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication (2024) · cites this paper as [10]
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Cited by
Sorted by citations
Solid-State Diffusion Bonding of Aluminum to Copper for Bimetallic Anode Fabrication
de Prado, J., Børresen, B. T., Utrilla, V., & Ureña, A. (2024) · Materials · doi:10.3390/ma17215333 · Cited by 6
“…structural damage from excessive volume changes during the charge– discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
Background
Metadata
- Authors
- Oltean, G., Tai, C.-W., Edström, K., & Nyholm, L.
- Affiliations
- Uppsala University (SE)
- Stockholm University (SE)
- Corresponding author
- Nyholm, Leif
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2014-12
- Volume
- 269
- Pages
- 266-273
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2059371965
- Cited by
- 56
- References
- 0
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 9 · 2023: 6 · 2022: 6 · 2021: 5 · 2020: 4 · 2019: 6 · 2018: 2 · 2017: 5 · 2016: 2 · 2015: 1
- FWCI
- 1.42
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Funders
- The Swedish Research council (2011-3506)
- The Ångström Advanced Battery Center (2012-4681)
- StandUp for Energy and The Swedish Energy Agency
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, capacity fade, native oxide, alumina coatings, dealloying, volume expansion, cycling stability, pouch cells
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