Cited by 56Advancements in Battery MaterialsBattery Modeling and ManagementAdvanced Battery Materials and Technologies

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On the origin of the capacity fading for aluminium negative electrodes in Li-ion batteries

Oltean, Gabriel, Tai, Cheuk-Wai, Edström, Kristina, Nyholm, Leif·2014·Journal of Power Sources

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Crossref · 10.1016/j.jpowsour.2014.06.118

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  • Pure aluminum anode capacity fading is caused by structural damage from excessive volume changes during charge-discharge, leading to crack nucleation and pulverization and loss of electrical contact.

    “The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”
  • Pure aluminum anode capacity fading is caused by loss of lithium due to diffusion into the bulk or formation of stable AlLi phases.

    “The causes of this have been extensively studied and include: (i) structural damage from excessive volume changes during the charge–discharge cycle, leading to (ii) crack nucleation and eventual pulverization of the anode, resulting in loss of electrical contact, and (iii) loss of lithium due to diffusion into the bulk or formation of stable AlLi phases [9,10].”

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Metadata

Authors
Oltean, G., Tai, C.-W., Edström, K., & Nyholm, L.
Affiliations
  • Uppsala University (SE)
  • Stockholm University (SE)
Corresponding author
Nyholm, Leif
Venue
Journal of Power Sources
Publisher
Elsevier BV
Published
2014-12
Volume
269
Pages
266-273
ISSN
0378-7753 (ISSN-L)
OpenAlex
W2059371965
Cited by
56
References
0
Citations by year
2026: 4 · 2025: 6 · 2024: 9 · 2023: 6 · 2022: 6 · 2021: 5 · 2020: 4 · 2019: 6 · 2018: 2 · 2017: 5 · 2016: 2 · 2015: 1
FWCI
1.42
Type
journal article
Language
en
Open access
closed
Locations
Journal of Power Sources (publishedVersion)
Funders
  • The Swedish Research council (2011-3506)
  • The Ångström Advanced Battery Center (2012-4681)
  • StandUp for Energy and The Swedish Energy Agency
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Keywords
lithium-ion batteries, capacity fade, native oxide, alumina coatings, dealloying, volume expansion, cycling stability, pouch cells

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