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Improving the graphite/electrolyte interface in lithium-ion battery for fast charging and low temperature operation: Fluorosulfonyl isocyanate as electrolyte additive
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In the citing paper
“It was reported that isocyanate-based additives can be electrochemically polymerized and form polyamide-like SEIs.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [128]
In the citing paper
“One problem of using FI as additive is the low initial Coulombic efficiency, caused by the consumption of Li through SEI formation during the first cycle.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [128]
In the citing paper
“Although the inorganic layer was thicker by using FI, it is mainly composed of LiF, ROSO 2 Li, Li 2 S, Li 2 SO 3 and a low concentration of Li 2 CO 3 , Li 2 O and Li x PF y O z , resulting in overall lower interface resistance.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [128]
In the citing paper
“The thickness reduction of the organic species layer was attributed to the suppression of carbonate solvent decomposition, while the increased thickness of the inorganic layer was attributed to the FI-derived SEI components.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [128]
In the citing paper
“They reported that compared with the SEI formed in conventional carbonate electrolytes without FI additive, the SEI formed in the electrolyte with FI additive was thicker, having thicker inorganic layers but thinner organic layers (Fig. 14c).”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [128]
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“Shi et al. [128] used fluorosulfonyl isocyanate (FI) to improve the LT performance.”
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Beheshti, S. H., Javanbakht, M., Omidvar, H., Behi, H., Zhu, X., Mamme, M. H., Hubin, A., Mierlo, J. V., & Berecibar, M. (2021) · Energies · doi:10.3390/en14217352 · Cited by 8
“Among these, p-toluenesulfonyl isocyanate [17], 3-(phenylsulfonyl) propionitrile [18], fluorosulfonyl isocyanate [19], and, p-toluenesulfonyl methyl isocyanide [20] could be mentioned as examples which contain different nitrogen-based and sulfur-based groups in their molecular structures.”
BackgroundCui, Z., Li, B.-Y., Xiong, H., Li, T., Xie, M.-X., Hu, J.-Y., Qiu, X., Gui, Z.-Q., Zhou, R., Shi, L.-L., et al. (2025) · New Carbon Materials · doi:10.1016/s1872-5805(25)61022-5 · Cited by 5
Zhao, Z.-X., Bai, X., Zhu, H.-L., Liu, W., Qi, Y.-X., Li, T., & Bai, Y.-J. (2022) · ACS Applied Electronic Materials · doi:10.1021/acsaelm.2c00939 · Cited by 5
Zhang, L., Zuo, X., Zhu, T., Lei, W., Xie, D.-M., Liu, J.-S., Xiao, X., Chen, X.-L., & Nan, J. (2021) · ChemElectroChem · doi:10.1002/celc.202100352 · Cited by 4
Yelwa, J. M., Fetuga, I. A., Musa, H., David, I., Makinde, P. F., Adesanya, M. A., Adedokun, O. J., Uwaike, T. I., Hammed, V. O., Ebereonwu, P. U., et al. (2026) · Journal of Power Sources · doi:10.1016/j.jpowsour.2026.240058 · Cited by 3
Liu, D., Kong, D., Yang, Q., He, Y.-L., & Hu, H.-J. (2024) · RSC Advances · doi:10.1039/d4ra03289f · Cited by 3
Synergistic Interfacial‐Bulk Solvation Enables Fast‐Charging and Low Temperature Li‐Ion Batteries
Hu, Y., Yao, T., Yang, Y., Xu, T., Gu, H.-H., Chen, D., Liu, Z., Tong, H., & Shen, L.-F. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202518935 · Cited by 2
Lv, P., Huo, T.-R., Gao, S., Li, P.-C., Li, P.-C., Guo, Z.-Y., Shi, J.-J., Zhang, D., Xie, S., He, Y., et al. (2024) · ACS Applied Nano Materials · doi:10.1021/acsanm.4c05756 · Cited by 2
Self-citationTang, X., Qi, S.-H., He, J., Liu, J.-D., Li, X., Lin, J., Alodhayb, A., Wang, L., & Ma, J. (2024) · Chinese Chemical Letters · doi:10.1016/j.cclet.2024.110622 · Cited by 2
Self-citationFang, C., Tran, T.-N., Ahmed, F., Hubble, D., Fu, Y., McCloskey, B., Battaglia, V., & Liu, G. (2023) · Electrochemistry communications · doi:10.1016/j.elecom.2023.107489 · Cited by 2
Application of Fast-Charging Graphite-Anode Lithium-Ion Batteries in Black Start
Chen, Y., Zuo, J., He, X., Zhang, S., & Bao, B. (2023) · Journal of Physics, Conference Series · doi:10.1088/1742-6596/2473/1/012018 · Cited by 2
Mohammed, A. G., Hasini, H., Elfeky, K. E., Ali, M. H., & Wang, Q. (2026) · Renewable & Sustainable Energy Reviews · doi:10.1016/j.rser.2026.117144 · Cited by 2
Electrolyte Design for Fast‐Charging Lithium‐Based Batteries
Liu, C., Cui, Z., & Manthiram, A. (2026) · Advanced Materials · doi:10.1002/adma.74532 · Cited by 2
“…] Diphenyl sulfone DPS [ 143 ] Bis(4-florophenyl) sulfone BFS [ 143 ] (trimethylsilyl)isothiocyanate TMSNCS [ 144 ] Fluorosulfonyl isocyanate FI [ 145 ] Vinylsulfonyl fluoride VSF [ 146 ] Isosorbide 2,5-dimethanesulfonate ISDMS [ 147 ] Other types Hexafluoroglutaric anhydride HFA [ 127 ]…”
Lin, K., Wu, J., Song, Z., Yi, Y., Peng, F., Wang, S., Zou, Z., Lan, T., Wu, J., & Jiang, C. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.179329 · Cited by 1
Zhou, M.-J., Ren, X.-C., Yao, J., Chen, C., Chen, P., Feng, J., Yang, Y., Xu, Q.-S., & Yan, K.-Y. (2026) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2026.07.024 · Cited by 1
Metadata
- Authors
- Shi, J., Ehteshami, N., Ma, J., Zhang, H., Liu, H., Zhang, X., Li, J., & Paillard, E.
- Affiliations
- Forschungszentrum Jülich (DE)
- State Key Laboratory of Chemical Resource Engineering (CN)
- University of Münster (DE)
- Corresponding author
- Shi, Junli
- Zhang, Xin
- Paillard, Elie
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2019-07
- Volume
- 429
- Pages
- 67-74
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2944777829
- Cited by
- 147
- References
- 0
- Citations by year
- 2026: 17 · 2025: 11 · 2024: 24 · 2023: 25 · 2022: 22 · 2021: 30 · 2020: 18
- FWCI
- 6.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Ningbo Institute of Materials Technology and Engineering, CAS Institutional Repository (submittedVersion)
- JuSER (Forschungszentrum Jülich) (submittedVersion)
- Virtual Community of Pathological Anatomy (University of Castilla La Mancha) (submittedVersion)
- Funders
- China Scholarship Council (CSC) ([2016]3035)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- solid electrolyte interphase, electrolyte additives, graphite anode, lithium-ion batteries, fast charging, low-temperature operation, interfacial resistance, rate capability
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