Removal of nickel (II) ions from water by Jordan natural zeolite as sorbent material
Open accessAbstract
In various laboratory conditions Ni2+ was investigated and isolated in tone from aquatic solutions using Jordanian natural zeolite (JNZ). The used JNZ was obtained from central Jordan. The used size fraction is (1.0–0.3 mm) which can be used as ion exchanger bed. The effects of time of interaction, initial metal concentration, adsorbent dose concentration and temperature were examined in the removal experiments. The maximum sorption capacity is accomplished at pH 4. The removal rate of Ni(II) was calculated to be for zeolite sample of 0.02 g and 20 mg.L-1 as a preliminary Ni concentration with 4 hrs of contact time. The adsorption efficiency was observed in 153.846 mg.g−1. The JNZ adsorbent's equilibrium adsorption potential was calculated and extrapolated using the Langmuir and Freundlich isotherm models. The results show that the experimental results were better matched using Langmuir model. The adsorption behavior of JNZ for the removal of Ni2+ was well-described using the pseudo-second-order kinetic model. In this research, many thermodynamic properties were determined, such as entropy (ΔS), enthalpy (ΔH) and free energy (ΔG). Intraparticle diffusion analysis was also conducted.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The Langmuir model is the best-fitting model for the adsorption of heavy metals in zeolites.
“According to the literature, the Langmuir model is the best-fitting model for the adsorption of heavy metals in zeolites.”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Al-Abbad and Al Dwairi, 2021
Section 3.3 and Table 2 report a better fit for the Freundlich model (R² = 0.998) than for Langmuir (R² = 0.908). The paper identifies Freundlich, not Langmuir, as well suited to its equilibrium data. Its experiment concerns Ni(II) on Jordanian natural zeolite, not heavy metals in zeolites generally; page numbers were not supplied in the passages. (LLM, conf=0.90)
Checked by a reasoning model — may be wrong.
Experimental — accuracy not yet measured
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
Natural zeolites as effective adsorbents in water and wastewater treatment
Wang, S., & Peng, Y. (2010) · Chemical Engineering Journal · doi:10.1016/j.cej.2009.10.029 · Cited by 2,441 · cited 1× · see citing works
“This could result from an increase in the amount of reactant collision, which could result in the observed increase in reaction rate and capability according to the theory of collision [39].”
Application of natural zeolites in environmental remediation: a short review
Misaelides, P. (2011) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2011.03.024 · Cited by 444 · see citing works
Flagged first, then by citations
Research works printed but not linked: 39
- A.A. Basheer, Chemical chiral pollution: impact on the society and science and need of the regulations in the 21 st century, Chirality 30 (4) (2018) 402-406, https://doi.org/10.1002/ chir.22808. · DOI
- A.A. Basheer, I. Ali, Stereoselective uptake and degradation of (±)-o, p-DDD pesticide stereomers in water-sediment system, Chirality 30 (9) (2018) 1088-1095, https://doi.org/10.1002/ chir.22989. · DOI
- A. Basheer, New generation nano-adsorbents for the removal of emerging contaminants in water, J. Mol. Liq. 261 (2018) 583- 593, https://doi.org/10.1016/j.molliq.2018.04.021. · DOI
- I. Ali, C.K. Jain, Groundwater contamination and health hazards by some of the most commonly used pesticides, Curr. Sci. 75 (1998) 1011-1014. https://www.jstor.org/stable/24101777.
- I. Ali, V. Gupta, H. Aboul-Enein, Metal ion speciation and capillary electrophoresis: Application in the new millennium, Electrophoresis 26 (21) (2005) 3988-4002, https://doi.org/ 10.1002/elps.200500216. · DOI
- I. Ali, O.M.L. Alharbi, Z.A. ALOthman, A.M. Al-Mohaimeed, A. Alwarthan, Modeling of fenuron pesticide adsorption on CNTs for mechanistic insight and removal in water, Environ. Res. 170 (2019) 389-397, https://doi.org/10.1016/j.envres.2018.12.066. · DOI
- E.A. Burakova, T.P. Dyachkova, A.V. Rukhov, E.N. Tugolukov, E.V. Galunin, A.G. Tkachev, A.A. Basheer, I. Ali, Novel and economic method of carbon nanotubes synthesis on a nickel magnesium oxide catalyst using microwave radiation, J. Mol. Liq. 253 (2018) 340-346, https://doi.org/10.1016/ j.molliq.2018.01.062. · DOI
- I. Ali, Microwave assisted economic synthesis of multi walled carbon nanotubes for arsenic species removal in water: batch and column operations, J. Mol. Liq. 271 (2018) 677-682, https:// doi.org/10.1016/j.molliq.2018.09.021. · DOI
- I. Ali, H.Y. Aboul-Enein, Speciation of metal ions by capillary electrophoresis, Crit. Rev. Anal. Chem. 32 (4) (2002) 337-350, https://doi.org/10.1080/10408340290765597. · DOI
- I. Ali, O.M.L. Alharbi, Z.A. Alothman, A. Alwarthan, Facile and eco-friendly synthesis of functionalized iron nanoparticles for cyanazine removal in water, Colloids & Surfaces B: Biointerfaces 171 (2018) 606-613, https://doi.org/10.1016/ j.colsurfb.2018.07.071. · DOI
- I. Ali, O.M.L. Alharbi, Z.A. Alothman, A.Y. Badjah, Kinetics, thermodynamics, and modeling of amido black dye photodegradation in water using Co/TiO 2 nanoparticles, Photochem. Photobiol. 94 (5) (2018) 935-941, https://doi.org/ 10.1111/php.2018.94.issue-510.1111/php.12937. · DOI
- I. Ali, O.M.L. Alharbi, Z.A. ALOthman, A. Alwarthan, A.M. Al-Mohaimeed, Preparation of a carboxymethylcellulose-iron composite for uptake of atorvastatin in water, Int. J. Biol. Macromol. 132 (2019) 244-253, https://doi.org/10.1016/j. ijbiomac.2019.03.211. · DOI
- I. Ali, A.E. Burakov, A.V. Melezhik, A.V. Babkin, I.V. Burakova, Ms. E.A. Neskomornaya, E.V. Galunin, A.G. Tkachev, D.V. Kuznetsov, Removal of copper (II) and Zinc (II) Ions in Water on a Newly Synthesized Polyhydroquinone/ Graphene Nanocomposite Material: Kinetics, Thermodynamics and Mechanism, Chem. Select 4 (2019) 12708-12718 doi: 10.1002/slct.201902657. · DOI
- N.H. Al-Shaalan, H. Alabdulmonem, High performance removal and simulation studies of diuron pesticide in water on MWCNTs, J. Mol. Liq. 289 (2019) 111039, https://doi.org/ 10.1016/j.molliq.2019.111039. · DOI
- I. Ali, T.A. Khan, I. Hussain, Treatment and remediation methods for arsenic removal from the ground water, Int. J. Environ. Eng. 3 (2011) 48-71, https://doi.org/10.1504/ IJEE.2011.037873. · DOI
- I. Ali, O. M. L. Alharbi, A. Tkachev, E. Galunin, A. Burakov, V. A. Grachev, Water treatment by new-generation graphene materials: hope for bright future. Environ. Sci. &Pollut. Res 25 (2018) 7315-7329 doi: 10.1007/s11356-018-1315-9. · DOI
- K. Kadirvelu, K. Thamaraiselvi, C. Namasivayam, Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from coirpitch, Sep. Purif. Technol. 24 (2001) 497-505, https://doi.org/10.1016/S1383-5866(01)00149-6. · DOI
- N. Akhtar, J. Iqbal, M. Iqbal, Removal and recovery of nickel (II) from aqueous solution by loofa sponge-immobilized biomass of chlorella sorokiniana: characterization studies, J. Hazard. Mater. B 108 (2004) 85-94, https://doi.org/10.1016/j. jhazmat.2004.01.002. · DOI
- S.S. Arain, T.G. Kazi, J.B. Arain, H.I. Afridi, A.G. Kazi, S. Nasreen, K.D. Brahman, Determination of nickel in blood and serum samples of oropharyngeal cancer patients consumed smokeless tobacco products by cloud point extraction coupled with flame atomic absorption spectrometry, Environ. Sci. Pollut. Res. 21 (20) (2014) 12017-12027, https://doi.org/10.1007/s11356- 014-3091-5. · DOI
- L. Fang, W. Li, H. Chen, F. Xiao, L. Huang, P.E. Holm, H.C.B. Hansen, D. Wang, Synergistic effect of humic and fulvic acids on Ni removal by the calcined Mg/Al layered double hydroxide, RSC Adv. 5 (24) (2015) 18866-18874, https://doi.org/10.1039/ C4RA15406A. · DOI
- R. Al Dwairi, Characterization of the Jordanian zeolitic tuff and its potential use in Khirbet es Samra wastewater treatment plant. Unpublished PhD Thesis, The University of Jordan, Amman, Jordan 185 P, 2007.
- R. Al Dwairi, W. Omar Al-Harahsheh, S. Kinetic modelling for heavy metal adsorption using Jordanian low-cost natural zeolite (fixed bed column study). Journal of Water Reuse and Desalination. 5(2) (2015) 231-238.
- M. Gougazeh, J. Buhl. Synthesis and characterization of zeolite A by hydrothermal transformation of natural Jordanian kaolin. Journal of Association of Arab Universities for Basic and Applied Sciences.15 (2014)35-42.
- F. Alakhras, H. Al-Shahrani, E. Al-Abbad, Al-Rimawi, N. Ouerfelli, Removal of Pb(II) metal ions from aqueous solutions using chitosan-vanillin derivatives of chelating polymers. Pol. J. Environ. Stud. Vol. 28, No. 3 (2019), 1523-1534.
- N. Negm, R. El Sheikh, A. El-Farargy, H.H. Hefni, M. Bekhit, Treatment of industrial wastewater containing copper and cobalt ions using modified chitosan, J. Ind. Eng. Chem. 21 (2015) 526-534, https://doi.org/10.1016/j.jiec.2014.03.015. · DOI
- R.L. Ramos, L.A. Jacome, M.J. Barron, F.L. Rubio, R.M. Coronado, Adsorption of zinc (II) from an aqueous solution onto activated carbon, J. Hazard. Mater. 90 (2002) 27-38, https://doi.org/10.1260/02636170360744056. · DOI
- K.S. Papageorgiou, K.F. Katsaros, P.E. Kouvelos, W.J. Nolan, H. Ledeit, K.N. Kanellopoulos, Heavy metal sorption by calcium alginate beads from Laminaria digitata, J. Hazard. Mater. 137 (3) (2006) 1765-1772, https://doi.org/10.1016/j. jhazmat.2006.05.017. · DOI
- S. Kundu, A.K. Gupta, Arsenic adsorption onto iron oxide- coated cement (IOCC): regression analysis of equilibrium data with several isotherm models and their optimization, Chem. Eng. 122 (1-2) (2006) 93-106, https://doi.org/10.1016/j. cej.2006.06.002. · DOI · Paper page
- O Hamdaoui, E Naffrechoux, Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part I. Twoparameter models and equations allowing determination of thermodynamic parameters, J. Hazard. Mater. 147 (1-2) (2007) 381-394, https://doi.org/10.1016/j. jhazmat.2007.01.021. · DOI
- C. Camilo, G. Carmen, M. Paula, Sorption characteristics of heavy metal ions by a natural zeolite, Chem. Technol. Biotechnol. 80 (4) (2005) 477-481, https://doi.org/10.1002/jctb. v80:410.1002/jctb.1189. · DOI
- M. Al-Anber, Z. Al-Anber, Utilization of natural zeolite as ion- exchange and sorbent material in the removal of iron, Desalination 225 (1-3) (2008) 70-81, https://doi.org/10.1016/j. desal.2007.07.006. · DOI
- M.T. Amin, A.A. Alazba, M. Shafiq, Comparative sorption of nickel from an aqueous solution using biochar derived from banana and orange peel using a batch system: kinetic and isotherm models. Arabian J. Sci. Eng., 44 (2019) 10105-10116. doi: 10.1007/s13369-019-03907-6. · DOI
- M. Deravanesiyan, M. Beheshti, A. Malekpour, The removal of Cr (III) and Co (II) ions from aqueous solution by two mechanisms using a new sorbent (alumina nanoparticles immobilized zeolite) - equilibrium, kinetic and thermodynamic studies, J. Molecular Liquids 209 (2015) 246- 257, https://doi.org/10.1016/j.molliq.2015.05.038. · DOI
- X.X. Liang, X. Ouyang, S. Wang, L. Yang, F. Huang, C. Ji, X. Chen, Efficient adsorption of Pb(II) from aqueous solutions using aminopropyltriethoxysilane-modified magnetic attapulgite@chitosan (APTS-Fe 3 O 4 /APT@CS) composite hydrogel beads, Int. J. Biol. Macromol. 137 (2019) 741-750, https://doi.org/10.1016/j.ijbiomac.2019.06.244. · DOI
- Y. Liu, X. Hu, Kinetics and thermodynamics of efficient phosphorus removal by a composite fiber, Appl. Sci. 9 (2019) 2220, https://doi.org/10.3390/app9112220. · DOI
- C. Fan, K. Li, J. Li, D. Ying, Y. Wang, J. Jia, Comparative and competitive adsorption of Pb(II) and Cu(II) using tetraethylenepentamine modified chitosan/CoFe 2 O 4 particles, J. Hazard. Mater. 326 (2017) 211-220, https://doi.org/10.1016/ j.jhazmat.2016.12.036. · DOI
- H.B. Hameed, M.I. EL-Khaiary, Malachite Green adsorption by rattan sawdust. Isotherm, kinetic, J. Hazard. Mater. 159 (2008) 574-579. doi: 10.1016/j.jhazmat.2008.02.054. · DOI
- V. Manirethan, K. Raval, R. Rajan, H. Thaira, R.M. Balakrishnan, Kinetic and thermodynamic studies on the adsorption of heavy metals from aqueous solution by melanin nanopigment obtained from marine source: Pseudomonas stutzeri, J. Environ. Manage. 214 (2018) 315-324, https://doi. org/10.1016/j.jenvman.2018.02.084. · DOI
- H. Demiral, C. Gu¨ngo¨r, Adsorption of copper (II) from aqueous solutions on activated carbon prepared from grape bagasse, J. Cleaner Prod. 124 (2016) 103-113, https://doi.org/10.1016/j. jclepro.2016.02.084. · DOI
Cited by
Sorted by citations
Adsorption of heavy metals on natural zeolites: A review
Velarde, L., Nabavi, M. S., Escalera, E., Antti, M.-L., & Akhtar, F. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.138508 · Cited by 491 · see citing works
- Authors
- Al-Abbad, E. A., & Al Dwairi, R. A.
- Venue
- Journal of Saudi Chemical Society
- Published
- 2021-05
- Volume
- 25
- Issue
- 5
- Pages
- 101233
- ISSN
- 1319-6103 (ISSN-L)
- OpenAlex
- W3150564821
- Cited by
- 41
- References
- 2
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 13 · 2023: 11 · 2022: 7 · 2021: 4
- FWCI
- 2.61
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Journal of Saudi Chemical Society (publishedVersion, cc-by-nc-nd)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- University of Dammam
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- nickel removal, nickel adsorption, natural zeolite, zeolite adsorbents, heavy metal removal from water, Langmuir isotherm, Freundlich isotherm, pseudo-second-order kinetics, adsorption thermodynamics, intraparticle diffusion, ion exchange
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review