Cited by 41Adsorption and biosorption for pollutant removalChemical Synthesis and CharacterizationEnvironmental remediation with nanomaterials

Removal of nickel (II) ions from water by Jordan natural zeolite as sorbent material

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Al-Abbad, Eman A., Al Dwairi, Reyad A.·2021·Journal of Saudi Chemical Society

Abstract

In various laboratory conditions Ni2+ was investigated and isolated in tone from aquatic solutions using Jordanian natural zeolite (JNZ). The used JNZ was obtained from central Jordan. The used size fraction is (1.0–0.3 mm) which can be used as ion exchanger bed. The effects of time of interaction, initial metal concentration, adsorbent dose concentration and temperature were examined in the removal experiments. The maximum sorption capacity is accomplished at pH 4. The removal rate of Ni(II) was calculated to be for zeolite sample of 0.02 g and 20 mg.L-1 as a preliminary Ni concentration with 4 hrs of contact time. The adsorption efficiency was observed in 153.846 mg.g−1. The JNZ adsorbent's equilibrium adsorption potential was calculated and extrapolated using the Langmuir and Freundlich isotherm models. The results show that the experimental results were better matched using Langmuir model. The adsorption behavior of JNZ for the removal of Ni2+ was well-described using the pseudo-second-order kinetic model. In this research, many thermodynamic properties were determined, such as entropy (ΔS), enthalpy (ΔH) and free energy (ΔG). Intraparticle diffusion analysis was also conducted.

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  • The Langmuir model is the best-fitting model for the adsorption of heavy metals in zeolites.

    “According to the literature, the Langmuir model is the best-fitting model for the adsorption of heavy metals in zeolites.”

    From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Al-Abbad and Al Dwairi, 2021

    Section 3.3 and Table 2 report a better fit for the Freundlich model (R² = 0.998) than for Langmuir (R² = 0.908). The paper identifies Freundlich, not Langmuir, as well suited to its equilibrium data. Its experiment concerns Ni(II) on Jordanian natural zeolite, not heavy metals in zeolites generally; page numbers were not supplied in the passages. (LLM, conf=0.90)

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Authors
Al-Abbad, E. A., & Al Dwairi, R. A.
Venue
Journal of Saudi Chemical Society
Published
2021-05
Volume
25
Issue
5
Pages
101233
ISSN
1319-6103 (ISSN-L)
OpenAlex
W3150564821
Cited by
41
References
2
Citations by year
2026: 3 · 2025: 3 · 2024: 13 · 2023: 11 · 2022: 7 · 2021: 4
FWCI
2.61
Type
journal article
Language
en
Open access
Locations
  • Journal of Saudi Chemical Society (publishedVersion, cc-by-nc-nd)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
University of Dammam
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
  • Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
Keywords
nickel removal, nickel adsorption, natural zeolite, zeolite adsorbents, heavy metal removal from water, Langmuir isotherm, Freundlich isotherm, pseudo-second-order kinetics, adsorption thermodynamics, intraparticle diffusion, ion exchange

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