Equilibrium between dolomitization and dedolomitization of a global set of surface water samples: A new theoretical insight on the dolomite inorganic formation mechanism
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According to the latest thermodynamic study, modern seawater is not conducive to dolomitization, and seawater is favorable for dolomitization in only a few regions, such as Abu Dhabi, the Mediterranean and the hypersaline lagoons in Brazil.
“Modern seawater is located in the dedolomitization zone, and the seawater of Abu Dhabi, the Mediterranean, and the Persian Gulf is located in the dolomitization zone.”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [24]
The new CDGPE phase equilibrium model indicates that the increase in activity ratios of Mg2+ to Ca2+ and SO4 to HCO3, as well as more acidic condition, will promote dolomite precipitate.
“This model indicates that the increase in activity ratios of Mg 2+ to Ca 2+ and SO 2- 4 to HCO - 3 , as well as the more acidic condition, will promote dolomite precipitate [24].”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [24]
The new CDGPE model has proved reliable and useful in predicting surface water reported in dolomitization and dedolomitization, including modern seawater; modern seawater is located in the dedolomitization zone, and seawater of Abu Dhabi, the Mediterranean, and the Persian Gulf is located in the dolomitization zone.
“this model has proved reliable and useful in predicting the surface water reported in dolomitization and dedolomitization (including in modern seawater) (Figure 4); Modern seawater is located in the dedolomitization zone, and the seawater of Abu Dhabi, the Mediterranean, and the Persian Gulf is located in the dolomitization zone.”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [24]
SO4 may promote or catalyze dolomite precipitation.
“It has also been noted that SO 2- 4 may even be a catalyst for dolomite precipitation [102,103]”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [24]
Removal of sulfate by microbial sulfate reduction at surface temperatures is not the key factor inhibiting low-temperature dolomite formation; rather, sulfate may promote dolomite formation.
“the removal of sulfate by microbial sulfate reduction at surface temperatures is not the key factor in inhibiting the formation of low-temperature dolomite; rather, sulfate may promote the formation of dolomite [24,102,103].”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [24]
Cites
Land, L. S. (1998) · Aquatic Geochemistry · doi:10.1023/a:1009688315854 · Cited by 396 · see citing works
Microbially catalyzed dolomite formation: From near-surface to burial
Petrash, D. A., Bialik, O. M., Bontognali, T. R. R., Vasconcelos, C., Roberts, J. A., McKenzie, J. A., & Konhauser, K. O. (2017) · Earth-Science Reviews · doi:10.1016/j.earscirev.2017.06.015 · Cited by 338 · see citing works
Aradóttir, E. S. P., Sonnenthal, E. L., Björnsson, G., & Jónsson, H. (2012) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2012.02.006 · Cited by 214 · see citing works
Tentative kinetic model for dolomite precipitation rate and its application to dolomite distribution
Arvidson, R. S., & Mackenzie, F. T. (1997) · Aquatic Geochemistry · doi:10.1007/bf00119858 · Cited by 74 · see citing works
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Thermodynamic and Kinetic Studies of Dolomite Formation: A Review
Chen, C., Zhong, H., Wang, X., Ning, M., Wang, X., Ge, Y., Wang, H., Tang, R., & Hou, M. (2023) · Minerals · doi:10.3390/min13121479 · Cited by 43 · see citing works
Self-citation
- Authors
- Wang, X.
- Affiliations
- Chengdu University of Technology (CN)
- Corresponding author
- Wang, Xinyu
- Venue
- Marine Chemistry
- Publisher
- Elsevier BV
- Published
- 2021-09
- Volume
- 235
- Pages
- 104017
- ISSN
- 0304-4203 (ISSN-L)
- OpenAlex
- W3192849879
- Cited by
- 6
- References
- 4
- Citations by year
- 2026: 1 · 2025: 2 · 2023: 3
- FWCI
- 0.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Marine Chemistry (publishedVersion)
- Funders
- National Natural Science Foundation of China (41807357)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Karst Systems and Hydrogeology
- Keywords
- dolomitization, dedolomitization, saturation index, gypsum, dolomite problem, Permian-Triassic transition
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