Prediction of glass transition temperatures: Binary blends and copolymers
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A miscible PBAT/PLA (10/90) blend would have a single Tg at 42.2 °C according to the Fox equation.
“A miscible PBAT/PLA (10/90) blend would have a single Tg at 42.2 °C according to the calculation using the Fox equation.”
From Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties (2020) · cites this paper as [24]
If PBAT and PLA were miscible at the molecular level, then there should be a shift in the glass transition temperatures according to the Fox Equation.
“If PBAT and PLA were miscible at the molecular level, then there should be a shift in the glass transition temperatures according to the Fox Equation (1) [24]:”
From Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties (2020) · cites this paper as [24]
Glass transition temperatures of a binary polymer blend can reveal whether two components are miscible.
“Glass transition temperatures (Tg) of a binary polymer blend can reveal whether two components are miscible [24].”
From Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties (2020) · cites this paper as [24]
Full miscibility of a polymer blend is characterized by a single Tg; in a partially miscible system, there are two Tg values that depend on composition; immiscible polymers show two Tg values for pure components without changes at different compositions.
“The full miscibility of a polymer blend is characterized by a single Tg; In a partially miscible system, there are two Tg values that depend on the composition; Immiscible polymers show two Tg values for pure components without changes at different compositions.”
From Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties (2020) · cites this paper as [24]
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Liu, M., Wu, C., Jiao, Y., Xiong, S., & Zhou, C. (2013) · Journal of Materials Chemistry B · doi:10.1039/c3tb20084a · Cited by 365 · see citing works
Deng, Y., Yu, C., Wongwiwattana, P., & Thomas, N. L. (2018) · Journal of Polymers and the Environment · doi:10.1007/s10924-018-1256-x · Cited by 193 · see citing works
Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties
Su, S., Duhme, M., & Kopitzky, R. (2020) · Materials · doi:10.3390/ma13214897 · Cited by 159 · see citing works
Miscibility, mechanical and thermal properties of poly(lactic acid)/polyester-diol blends
Okamoto, K., Ichikawa, T., Yokohara, T., & Yamaguchi, M. (2009) · European Polymer Journal · doi:10.1016/j.eurpolymj.2009.05.011 · Cited by 85 · see citing works
- Authors
- Brostow, W., Chiu, R., Kalogeras, I. M., & Vassilikou-Dova, A.
- Affiliations
- University of North Texas (US)
- National and Kapodistrian University of Athens (GR)
- Corresponding author
- Brostow, Witold
- Venue
- Materials Letters
- Publisher
- Elsevier BV
- Published
- 2008-06
- Volume
- 62
- Issue
- 17-18
- Pages
- 3152-3155
- ISSN
- 0167-577X (ISSN-L)
- OpenAlex
- W2091818949
- Cited by
- 398
- References
- 0
- Citations by year
- 2026: 14 · 2025: 23 · 2024: 29 · 2023: 27 · 2022: 17 · 2021: 20 · 2020: 24 · 2019: 42 · 2018: 29 · 2017: 21 · 2016: 29 · 2015: 24 · 2014: 21 · 2013: 21 · 2012: 23
- FWCI
- 5.78
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Materials Letters (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Keywords
- glass transition temperature, polymer blends, copolymers, composition dependence, miscibility, Fox equation, Gordon-Taylor equation, Kwei equation, polymer composites
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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