The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
In-situ grown nanocrystal TiO2 on 2D Ti3C2 nanosheets for artificial photosynthesis of chemical fuels
Abstract
Abstract Artificial photosynthesis of high-valued chemicals is a promising route to alleviate global warming and energy crisis. Herein, a layered hybrid heterojunction of TiO2/Ti3C2 was synthesized by a facile hydrothermal oxidation method. The TiO2/Ti3C2 heterojunction was further functionalized by imine ligands and Pd nanoparticles, and used as a photocathode in CO2 reduction for the first time. These layered TiO2/Ti3C2 heterojunction materials have narrow band gap (2.1 eV), which contributes to the absorption of visible light. In the artificial photosynthetic cell of Pd/N-TiO2/Ti3C2||BiVO4, some hydrocarbon, such as formate, methanol and ethanol, were generated efficiently. The evolution rate of total hydrocarbon was as high as 73.6 μM cm−2 h−1 (36.8 mM h−1 g−1). The hydrogen gas can be evolved in the photoelectrocatalysis cell when the external voltage provided by Si solar cell is as low as − 0.4 V, due to the high activity of the heterojunction structure. The highest apparent light quantum efficiency of artificial photosynthesis cell was 1.78% at − 1.0 V. The carbon source of products was derived from CO2, which was verified by 13CO2 labeling experiments. The experimental results suggest that the in-situ formed TiO2/Ti3C2 heterojunction materials can be employed as candidates for efficiently photoelectrocatalytic reduction of CO2 to chemical fuels.
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Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Self-citationRecent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Cited by
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Li, B., Lai, C., Zeng, G., Huang, D., Qin, L., Zhang, M., Cheng, M., Liu, X., Yi, H., Zhou, C., et al. (2019) · Small · doi:10.1002/smll.201804565 · Cited by 367
Enhanced ammonia response of Ti3C2T nanosheets supported by TiO2 nanoparticles at room temperature
Tai, H., Duan, Z., He, Z., Li, X., Xu, J., Liu, B., & Jiang, Y. (2019) · Sensors and Actuators B: Chemical · doi:10.1016/j.snb.2019.126874 · Cited by 325
Ti3C2 2D MXene: Recent Progress and Perspectives in Photocatalysis
Tang, R., Xiong, S., Gong, D., Deng, Y., Wang, Y., Su, L., Ding, C., Yang, L., & Liao, C. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c12905 · Cited by 259
Titanium carbide nanosheets with defect structure for photothermal-enhanced sonodynamic therapy
Li, G., Zhong, X., Wang, X., Gong, F., Lei, H., Zhou, Y., Li, C., Xiao, Z., Ren, G., Zhang, L., et al. (2022) · Bioactive Materials · doi:10.1016/j.bioactmat.2021.06.021 · Cited by 151
Metadata
- Authors
- Xu, Y., Wang, S., Yang, J., Han, B., Nie, R., Wang, J., Wang, J., & Jing, H.
- Venue
- Nano Energy
- Publisher
- Elsevier BV
- Published
- 2018-09
- Volume
- 51
- Pages
- 442-450
- ISSN
- 2211-2855 (ISSN-L)
- OpenAlex
- W2810673398
- Cited by
- 164
- References
- 3
- FWCI
- 4.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, Y., Wang, S., Yang, J., Han, B., Nie, R., Wang, J., Wang, J., & Jing, H. (2018). In-situ grown nanocrystal TiO2 on 2D Ti3C2 nanosheets for artificial photosynthesis of chemical fuels. Nano Energy. https://doi.org/10.1016/j.nanoen.2018.06.086
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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