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Cited by 258

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A universal synthesis strategy for single atom dispersed cobalt/metal clusters heterostructure boosting hydrogen evolution catalysis at all pH values

Yuan, Shuai, Pu, Zonghua, Zhou, Huang, Yu, Jun, Amiinu, Ibrahim Saana, Zhu, Jiawei, Liang, Qirui, Yang, Jinlong, He, Daping, Hu, Zhiyi, Van Tendeloo, Gustaaf, Mu, Shichun·2019·Nano Energy

Abstract

Abstract The development of a stable, efficient and economic catalyst for hydrogen evolution reaction (HER) of water splitting is one of the most hopeful approaches to confront the environmental and energy crisis. A two-step method is employed to obtain metal clusters (Ru, Pt, Pd etc.) combining single cobalt atoms anchored on nitrogen-doped carbon (Ru/Pt/Pd@Co-SAs/N-C). Based on the synergistic effect between Ru clusters and single cobalt atoms, Ru@Co-SAs/N-C exhibits an outstanding HER electrocatalytic activity. Specifically, Ru@Co-SAs/N-C only needs 7 mV overpotential at 10 mA cm-2 in 1 M KOH solution, which is much better than commercial 20 wt% Pt/C (40 mV) catalyst. Density functional theory (DFT) calculations further reveal the synergy effect between surface Ru nanoclusters and Co-SAs/N-C toward hydrogen adsorption for HER. Additionally, Ru@Co-SAs/N-C also exhibits excellent catalytic ability and durability under acidic and neutral media. The present study opens a new avenue towards the design of metal clusters/single cobalt atoms heterostructures with outstanding performance toward HER and beyond.

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Metadata

Authors
Yuan, S., Pu, Z., Zhou, H., Yu, J., Amiinu, I. S., Zhu, J., Liang, Q., Yang, J., He, D., Hu, Z., Van Tendeloo, G., & Mu, S.
Venue
Nano Energy
Publisher
Elsevier BV
Published
2019-05
Volume
59
Pages
472-480
ISSN
2211-2855 (ISSN-L)
OpenAlex
W2915998767
Cited by
258
References
8
FWCI
8.19
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A universal synthesis strategy for single atom dispersed cobalt/metal clusters heterostructure boosting hydrogen evolution catalysis at all pH values. https://app.cochat.ai/papers/10.1016/j.nanoen.2019.02.062
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Yuan, S., Pu, Z., Zhou, H., Yu, J., Amiinu, I. S., Zhu, J., Liang, Q., Yang, J., He, D., Hu, Z., Van Tendeloo, G., & Mu, S. (2019). A universal synthesis strategy for single atom dispersed cobalt/metal clusters heterostructure boosting hydrogen evolution catalysis at all pH values. Nano Energy. https://doi.org/10.1016/j.nanoen.2019.02.062

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