The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Edge-doping modulation of N, P-codoped porous carbon spheres for high-performance rechargeable Zn-air batteries
Abstract
Abstract The development of low-cost efficient bifunctional oxygen electrocatalysts is of importance for optimizing the performance of metal-air batteries. By using manganese dioxide spheres as both the redox initiator and the self-sacrificing template for the in-situ interfacial polymerization of aniline monomers, we demonstrated a facile approach to preparing porous polyaniline spheres in the presence of phytic acid. Subsequent pyrolysis led to nitrogen and phosphorous co-doped carbon spheres (NPCSs) with highly porous structure and good bifunctional electrocatalytic activities for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Specifically, NPCSs exhibited a comparable half-wave potential (0.83 V vs. RHE) to that of commercial Pt/C, but a larger current density, for ORR and was superior to RuO2 (overpotential, 320 mV) for OER with a smaller overpotential of 310 mV. The Density Functional Theory (DFT) calculations revealed firstly that the heteroatom-doping at the edges of the porous structure plays a dominate role in achieving the high bifunctional catalytic activities. Furthermore, the bifunctional oxygen electrocatalysis enabled the fabrication of high-performance Zn-air batteries in aqueous and solid-state electrolytes, exhibiting large energy density, high power density, and good cycling stability.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells
Qu, L., Liu, Y., Baek, J.-B., & Dai, L. (2010) · ACS Nano · doi:10.1021/nn901850u · Cited by 3,948
Self-citationA metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Self-citationMa, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5082553 · Cited by 1,846
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Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Defect Engineering on Electrode Materials for Rechargeable Batteries
Zhang, Y., Tao, L., Xie, C., Wang, D., Zou, Y., Chen, R., Wang, Y., Jia, C., & Wang, S. (2020) · Advanced Materials · doi:10.1002/adma.201905923 · Cited by 1,019
Self-citationHeteroatom-doped carbon-based materials for lithium and sodium ion batteries
Yuan, Y., Chen, Z., Yu, H., Zhang, X., Liu, T., Xia, M., Zheng, R., Shui, M., & Shu, J. (2020) · Energy Storage Materials · doi:10.1016/j.ensm.2020.07.027 · Cited by 455
Recent Advances in Non‐Noble Bifunctional Oxygen Electrocatalysts toward Large‐Scale Production
Zeng, K., Zheng, X., Li, C., Yan, J., Tian, J., Jin, C., Strasser, P., & Yang, R. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000503 · Cited by 365
Carbon‐Based Electrocatalysts for Acidic Oxygen Reduction Reaction
Cui, P., Zhao, L., Long, Y., Dai, L., & Hu, C. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202218269 · Cited by 267
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Metadata
- Authors
- Chen, S., Zhao, L., Ma, J., Wang, Y., Dai, L., & Zhang, J.
- Venue
- Nano Energy
- Publisher
- Elsevier BV
- Published
- 2019-06
- Volume
- 60
- Pages
- 536-544
- ISSN
- 2211-2855 (ISSN-L)
- OpenAlex
- W2933950946
- Cited by
- 300
- References
- 42
- FWCI
- 10.31
- Type
- journal article
- Language
- en
- Open access
- closed
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