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Synthesis of RuNi alloy nanostructures composed of multilayered nanosheets for highly efficient electrocatalytic hydrogen evolution

Liu, Guigao, Zhou, Wei, Chen, Bo, Zhang, Qinghua, Cui, Xiaoya, Li, Bing, Lai, Zhuangchai, Chen, Ye, Zhang, Zhicheng, Gu, Lin, Zhang, Hua·2019·Nano Energy

Abstract

Abstract Rational design and synthesis of materials for highly efficient electrocatalytic hydrogen evolution reaction (HER) is of paramount importance in the development and utilization of renewable energy. Here, RuNi alloy nanostructures (RuNi NSs) composed of multilayered nanosheets are prepared through a one-pot solvothermal process. Impressively, they exhibit a remarkable electrocatalytic HER activity under alkaline conditions with a low overpotential of only 15 mV at 10 mA cm−2 and a Tafel slope of only 28 mV dec−1, much better than those of commercial Ru/C and Pt/C catalysts. This superior performance could be attributed to their large electrochemically active surface area (154 m2 g−1), and the Ni alloying effect which facilitates the water dissociation and optimizes the hydrogen adsorption and desorption. This work paves the way to the rational design and synthesis of new materials for highly efficient electrocatalysis.

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Metadata

Authors
Liu, G., Zhou, W., Chen, B., Zhang, Q., Cui, X., Li, B., Lai, Z., Chen, Y., Zhang, Z., Gu, L., & Zhang, H.
Venue
Nano Energy
Publisher
Elsevier BV
Published
2019-12
Volume
66
Pages
104173
ISSN
2211-2855 (ISSN-L)
OpenAlex
W2980272560
Cited by
161
References
8
FWCI
4.12
Type
journal article
Language
en
Open access
closed

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Liu, G., Zhou, W., Chen, B., Zhang, Q., Cui, X., Li, B., Lai, Z., Chen, Y., Zhang, Z., Gu, L., & Zhang, H. (2019). Synthesis of RuNi alloy nanostructures composed of multilayered nanosheets for highly efficient electrocatalytic hydrogen evolution. Nano Energy. https://doi.org/10.1016/j.nanoen.2019.104173

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.