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Cited by 54Adsorption and biosorption for pollutant removalEnvironmental remediation with nanomaterialsCoagulation and Flocculation Studies

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Adsorption kinetics, equilibrium and thermodynamics of a textile dye V5BN by a natural nanocomplex material: Clinoptilolite

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Nannu Shankar, Sripriya, Dinakaran, Divakar Raj, Chandran, Dinesh Kumar, Mantha, Gopikrishna, Srinivasan, Bhuvaneswari, Nyayiru Kannaian, Udaya Prakash·2023·Energy Nexus
DOI 10.1016/j.nexus.2023.100197
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Abstract

Dyes are considered as a major pollutant released in industrial (leather, textile, and paper) effluents. In this study, the ability of Clinoptilolite in adsorbing an industrial dye (Violet 5BN) was assessed. Clinoptilolite was characterized by Scanning Electron Microscopy, Energy Dispersive analysis using X-ray and Brunauer, Emmett and Teller analysis. Batch studies at varying adsorbent dosage, pH, temperature, and time revealed that 96% of the dye was adsorbed with an adsorbent mass of 1.5 g at 30 °C, pH 5 and reaction time of 90 min. Both Langmuir and Freundlich isotherms were found to be fit, which proves the process to be heterogeneous. The experimental and calculated values of adsorption capacity were almost similar, with correlation coefficients greater than 0.9, thus implying pseudo-second order and intraparticle diffusion as the favorable models. Negative values of ΔG° indicate strong binding energy between the adsorbent and adsorbate, while negative ΔS° values prove less randomness of the process and higher adsorbate concentration on the adsorbent surface due to ion-exchange interaction. The exothermic nature of adsorption is evident from the negative ΔH° recorded. Thermodynamic studies showed the system was a spontaneous and enthalpy driven process, with chemisorption as the predominant mode of adsorption at 30 °C and physisorption at elevated temperatures. The study demonstrates the significance of natural clinoptilolite in environmental protection, as an adsorbent for remediation of dyes.

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Research works printed but not linked: 67

  1. Omer, 2017, Adsorption isothermal studies on the removal of bod and cod of a leather tannery effluent using clinoptilolite, Int. J. Chem. Res., 10, 496
  2. Wawrzkiewicz, 2015, Anion exchange resins as effective sorbents for removal of acid, reactive, and direct dyes from textile wastewaters, Ion Exch., 37
  3. Mall, 2006, Removal of Orange-G and methyl violet dyes by adsorption onto bagasse fly ash—kinetic study and equilibrium isotherm analyses, Dyes Pigment, 69, 210, 10.1016/j.dyepig.2005.03.013 · DOI
  4. Khattab, 2020, Textile dyeing industry: environmental impacts and remediation, Environ. Sci. Pollut. Res., 27, 3803, 10.1007/s11356-019-07137-z · DOI · Paper page
  5. Li, 2016, Removal of reactive dyes from wastewater assisted with kaolin clay by magnesium hydroxide coagulation process, Colloids Surf. A, 494, 222, 10.1016/j.colsurfa.2016.01.048 · DOI
  6. Hassan, 2018, A critical review on recent advancements of the removal of reactive dyes from dyehouse effluent by ion-exchange adsorbents, Chemosphere, 209, 201, 10.1016/j.chemosphere.2018.06.043 · DOI · Paper page
  7. Tang, 2016, Fe-Mn bi-metallic oxides loaded on granular activated carbon to enhance dye removal by catalytic ozonation, Environ. Sci. Pollut. Res., 23, 18800, 10.1007/s11356-016-7030-5 · DOI
  8. Ebrahiem, 2017, Removal of organic pollutants from industrial wastewater by applying photo-Fenton oxidation technology, Arab. J. Chem., 10, S1674, 10.1016/j.arabjc.2013.06.012 · DOI
  9. Mady, 2017, Facile microwave-assisted green synthesis of Ag-ZnFe2O4@ rGO nanocomposites for efficient removal of organic dyes under UV-and visible-light irradiation, Appl. Catal. B, 203, 416, 10.1016/j.apcatb.2016.10.033 · DOI
  10. Basturk, 2015, Decolorization of antraquinone dye Reactive Blue 181 solution by UV/H2O2 process, J. Photochem. Photobiol. A, 299, 67, 10.1016/j.jphotochem.2014.11.003 · DOI
  11. Zeng, 2016, Novel polyvinylidene fluoride nanofiltration membrane blended with functionalized halloysite nanotubes for dye and heavy metal ions removal, J. Hazard. Mater., 317, 60, 10.1016/j.jhazmat.2016.05.049 · DOI
  12. Long, 2017, Microbial fuel cell-photoelectrocatalytic cell combined system for the removal of azo dye wastewater, Bioresour. Technol., 244, 182, 10.1016/j.biortech.2017.07.088 · DOI
  13. Keskin, 2015, Removal of a reactive dye and hexavalent chromium by a reusable bacteria attached electrospun nanofibrous web, RSC Adv., 5, 86867, 10.1039/C5RA15601G · DOI
  14. Munck, 2018, Biofilm formation of filamentous fungi Coriolopsis sp. on simple muslin cloth to enhance removal of triphenylmethane dyes, J. Environ. Manag., 214, 261, 10.1016/j.jenvman.2018.03.025 · DOI
  15. Mokhtar, 2017, Biosorption of azo-dye using marine macro-alga of Euchema Spinosum, J. Environ. Chem. Eng., 5, 5721, 10.1016/j.jece.2017.10.043 · DOI
  16. Chiong, 2016, Enzymatic treatment of methyl orange dye in synthetic wastewater by plant-based peroxidase enzymes, J. Environ. Chem. Eng., 4, 2500, 10.1016/j.jece.2016.04.030 · DOI
  17. Bhatia, 2017, Biological methods for textile dye removal from wastewater: a review, Crit. Rev. Environ. Sci. Technol., 47, 1836, 10.1080/10643389.2017.1393263 · DOI · Paper page
  18. Zhou, 2014, Adsorption kinetic and equilibrium studies for methylene blue dye by partially hydrolyzed polyacrylamide/cellulose nanocrystal nanocomposite hydrogels, Chem. Eng. J., 251, 17, 10.1016/j.cej.2014.04.034 · DOI
  19. Zhang, 2020, Adsorption of dyes brilliant blue, sunset yellow and tartrazine from aqueous solution on chitosan: analytical interpretation via multilayer statistical physics model, Chem. Eng. J., 382, 10.1016/j.cej.2019.122952 · DOI
  20. Adeyemo, 2017, Adsorption of dyes using different types of clay: a review, Appl. Water Sci., 7, 543, 10.1007/s13201-015-0322-y · DOI · Paper page
  21. Wanassi, 2017, Carbonaceous adsorbents derived from textile cotton waste for the removal of Alizarin S dye from aqueous effluent: kinetic and equilibrium studies, Environ. Sci. Pollut. Res., 24, 10041, 10.1007/s11356-017-8410-1 · DOI
  22. Etim, 2016, Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution, J. Saudi Chem. Soc., 20, S67, 10.1016/j.jscs.2012.09.014 · DOI
  23. Rashtbari, 2020, Potential of using green adsorbent of humic acid removal from aqueous solutions: equilibrium, kinetics, thermodynamic and regeneration studies, Int. J. Environ. Anal. Chem., 1
  24. Maneerung, 2016, Activated carbon derived from carbon residue from biomass gasification and its application for dye adsorption: kinetics, isotherms and thermodynamic studies, Bioresour. Technol., 200, 350, 10.1016/j.biortech.2015.10.047 · DOI
  25. Nassar, 2016, Cobalt ferrite nanoparticles via a template-free hydrothermal route as an efficient nano-adsorbent for potential textile dye removal, RSC Adv., 6, 79688, 10.1039/C6RA12852A · DOI
  26. You, 2016, Selective removal of cationic dye from aqueous solution by low-cost adsorbent using phytic acid modified wheat straw, Colloids Surf. A, 509, 91, 10.1016/j.colsurfa.2016.08.085 · DOI
  27. Kraljević Pavelić, 2018, Critical review on zeolite clinoptilolite safety and medical applications in vivo, Front. Pharmacol., 9, 1350, 10.3389/fphar.2018.01350 · DOI · Paper page
  28. Hoseini, 2016, An oxalate selective electrode based on modified PVC-membrane with tetra-butylammonium—clinoptilolite nanoparticles, Mater. Sci. Eng. C, 60, 119, 10.1016/j.msec.2015.11.016 · DOI
  29. Nezamzadeh-Ejhieh, 2014, Effect of a nano-sized natural clinoptilolite modified by the hexadecyltrimethyl ammonium surfactant on cephalexin drug delivery, C. R. Chim., 17, 49, 10.1016/j.crci.2013.07.009 · DOI
  30. Behin, 2019, Recent advances in the science and technology of natural zeolites in Iran, Clay Miner., 54, 131, 10.1180/clm.2019.19 · DOI
  31. Nezamzadeh-Ejhieh, 2013, Sunlight photodecolorization of a mixture of Methyl Orange and Bromocresol Green by CuS incorporated in a clinoptilolite zeolite as a heterogeneous catalyst, J. Ind. Eng. Chem., 19, 1433, 10.1016/j.jiec.2013.01.006 · DOI
  32. Polat, 2004, Use of natural zeolite (clinoptilolite) in agriculture, J. Fruit Ornam. Plant Res., 12, 183
  33. Abukhadra, 2020, The effect of different green alkali modification processes on the clinoptilolite surface as adsorbent for ammonium ions; characterization and application, Microporous Mesoporous Mater., 300, 10.1016/j.micromeso.2020.110145 · DOI
  34. Li, 2019, Removal of Zn2+, Pb2+, Cd2+, and Cu2+ from aqueous solution by synthetic clinoptilolite, Microporous Mesoporous Mater., 273, 203, 10.1016/j.micromeso.2018.07.010 · DOI
  35. Nezamzadeh-Ejhieh, 2015, Heterogeneous photodegradation of 2, 4-dichlorophenol using FeO doped onto nano-particles of zeolite P, J. Ind. Eng. Chem., 21, 668, 10.1016/j.jiec.2014.03.035 · DOI
  36. Soori, 2018, Synergistic effects of copper oxide-zeolite nanoparticles composite on photocatalytic degradation of 2, 6-dimethylphenol aqueous solution, J. Mol. Liq., 255, 250, 10.1016/j.molliq.2018.01.169 · DOI
  37. Du, 2005, Ammonia removal from aqueous solution using natural Chinese clinoptilolite, Sep. Purif. Technol., 44, 229, 10.1016/j.seppur.2004.04.011 · DOI
  38. Qiu, 2009, Studies on the adsorption of dyes into clinoptilolite, Desalination, 243, 286, 10.1016/j.desal.2008.04.029 · DOI
  39. Wibowo, 2017, Reduction of seawater salinity by natural zeolite (Clinoptilolite): adsorption isotherms, thermodynamics and kinetics, Desalination, 409, 146, 10.1016/j.desal.2017.01.026 · DOI
  40. Rahmani-Aliabadi, 2018, A visible light FeS/Fe2S3/zeolite photocatalyst towards photodegradation of ciprofloxacin, J. Photochem. Photobiol. A, 357, 1, 10.1016/j.jphotochem.2018.02.006 · DOI
  41. Crini, 2006, Non-conventional low-cost adsorbents for dye removal: a review, Bioresour. Technol., 97, 1061, 10.1016/j.biortech.2005.05.001 · DOI · Paper page
  42. Derikvandi, 2017, A comprehensive study on electrochemical and photocatalytic activity of SnO2-ZnO/clinoptilolite nanoparticles, J. Mol. Catal. A Chem., 426, 158, 10.1016/j.molcata.2016.11.011 · DOI
  43. Ayawei, 2017, Modelling and interpretation of adsorption isotherms, J Chem, 2017
  44. Azizian, 2004, Kinetic models of sorption: a theoretical analysis, J. Colloid Interface Sci., 276, 47, 10.1016/j.jcis.2004.03.048 · DOI
  45. Wu, 2009, Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics, Chem. Eng. J., 153, 1
  46. Yousef, 2011, Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: kinetics, mechanism, and thermodynamics studies, Chem. Eng. J., 171, 1143, 10.1016/j.cej.2011.05.012 · DOI
  47. Heidari-Chaleshtori, 2015, Clinoptilolite nano-particles modified with aspartic acid for removal of Cu (II) from aqueous solutions: isotherms and kinetic aspects, New J. Chem., 39, 9396, 10.1039/C5NJ01631B · DOI
  48. Mahmoud, 2016, Textile dye removal from aqueous solutions using cheap MgO nanomaterials: adsorption kinetics, isotherm studies and thermodynamics, Adv. Powder Technol., 27, 223, 10.1016/j.apt.2015.12.006 · DOI
  49. Ogihara, 2000, Composition of clinoptilolite formed from volcanic glass during burial diagenesis, Clays Clay Miner., 48, 106, 10.1346/CCMN.2000.0480113 · DOI
  50. Thommes, 2015, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report), Pure Appl. Chem., 87, 1051, 10.1515/pac-2014-1117 · DOI · Paper page
  51. Armağan, 2004, Equilibrium studies on the adsorption of reactive azo dyes into zeolite, Desalination, 170, 33, 10.1016/j.desal.2004.02.091 · DOI
  52. Karadag, 2007, Basic and reactive dye removal using natural and modified zeolites, J. Chem. Eng. Data, 52, 2436, 10.1021/je7003726 · DOI
  53. Wang, 2005, Removal of dyes from aqueous solution using fly ash and red mud, Water Res., 39, 129, 10.1016/j.watres.2004.09.011 · DOI · Paper page
  54. Kamboh, 2011, A highly efficient calix [4]arene based resin for the removal of azo dyes, Desalination, 268, 83, 10.1016/j.desal.2010.10.001 · DOI
  55. Wang, 2006, Characterisation and environmental application of an Australian natural zeolite for basic dye removal from aqueous solution, J. Hazard. Mater., 136, 946, 10.1016/j.jhazmat.2006.01.038 · DOI
  56. Nezamzadeh-Ejhieh, 2010, Solar photodecolorization of methylene blue by CuO/X zeolite as a heterogeneous catalyst, Appl. Catal. A, 388, 149, 10.1016/j.apcata.2010.08.042 · DOI
  57. Nezamzadeh-Ejhieh, 2013, Decolorization of a binary azo dyes mixture using CuO incorporated nanozeolite-X as a heterogeneous catalyst and solar irradiation, Chem. Eng. J., 228, 631, 10.1016/j.cej.2013.05.035 · DOI
  58. Nezamzadeh-Ejhieh, 2014, Comparison of photocatalytic efficiency of supported CuO onto micro and nano particles of zeolite X in photodecolorization of Methylene blue and Methyl orange aqueous mixture, Appl. Catal. A, 477, 83, 10.1016/j.apcata.2014.02.031 · DOI
  59. Shah, 2013, High-value zeolitic material from bagasse fly ash: utilization for dye elimination, Water Environ. Res., 85, 558, 10.2175/106143013X13596524515744 · DOI
  60. Baocheng, 2008, Adsorption behavior of Azo Dye CI Acid Red 14 in aqueous solution on surface soils, J. Environ. Sci., 20, 704, 10.1016/S1001-0742(08)62116-6 · DOI
  61. Borandegi, 2015, Enhanced removal efficiency of clinoptilolite nano-particles toward Co (II) from aqueous solution by modification with glutamic acid, Colloids Surf. A, 479, 35, 10.1016/j.colsurfa.2015.03.040 · DOI
  62. Srivastava, 2006, Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics, Colloids Surf. A, 272, 89, 10.1016/j.colsurfa.2005.07.016 · DOI
  63. Alver, 2012, Anionic dye removal from aqueous solutions using modified zeolite: adsorption kinetics and isotherm studies, Chem. Eng. J., 200, 59, 10.1016/j.cej.2012.06.038 · DOI
  64. Vimonses, 2009, Adsorption of congo red by three Australian kaolins, Appl. Clay Sci., 43, 465, 10.1016/j.clay.2008.11.008 · DOI
  65. Anari-Anaraki, 2015, Modification of Iranian clinoptilolite nano-particles by hexadecyltrimethyl ammonium cationic surfactant and dithizone for removal of Pb (II) from aqueous solution, J. Colloid Interface Sci., 440, 272, 10.1016/j.jcis.2014.11.017 · DOI · Paper page
  66. Venkatesha, 2012, Kinetics and thermodynamics of reactive and vat dyes adsorption on MgO nanoparticles, Chem. Eng. J., 198, 1, 10.1016/j.cej.2012.05.071 · DOI
  67. Liu, 2009, Is the free energy change of adsorption correctly calculated?, J. Chem. Eng. Data, 54, 1981, 10.1021/je800661q · DOI

Cited by

Sorted by citations

Metadata

Authors
Nannu Shankar, S., Dinakaran, D. R., Chandran, D. K., Mantha, G., Srinivasan, B., & Nyayiru Kannaian, U. P.
Affiliations
Kuwait Institute for Scientific Research (KW)
ORCID
Venue
Energy Nexus
Publisher
Elsevier BV
Published
2023-06
Volume
10
Pages
100197
ISSN
2772-4271 (ISSN-L)
DOI
10.1016/j.nexus.2023.100197
OpenAlex
W4367043501
Cited by
54
References
0
Citations by year
2026: 10 · 2025: 28 · 2024: 14 · 2023: 2
FWCI
4.32
Type
journal article
Language
en
Open access
Licence
Locations
  • Energy Nexus (publishedVersion, cc-by)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
  • Physical Sciences › Environmental Science › Water Science and Technology › Coagulation and Flocculation Studies
Keywords
dye adsorption, clinoptilolite, textile dyes, adsorption kinetics, adsorption isotherms, adsorption thermodynamics, pseudo-second-order kinetics, intraparticle diffusion, Langmuir isotherm, Freundlich isotherm, chemisorption, physisorption, dye wastewater treatment

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