Toughening of poly(l-lactide) with poly(ε-caprolactone): Combined effects of matrix crystallization and impact modifier particle size
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At 80 °C, the modulus of PLA/PCL (80/20) blends with a high-crystallinity PLA matrix was 20 times higher than the modulus of an analogous blend with a low-crystallinity PLA matrix.
“Bai et al. (2013) found that the modulus of PLA/PCL (80/20) blends with a high-crystallinity PLA matrix was 20 times higher than the modulus of an analogous blend with a low-crystallinity of PLA matrix at the temperature of 80 • C.”
From Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review (2019) · cites this paper as Bai et al., 2013
For PLA/PCL (80/20) blends with high PLA crystallinity (46-48%), the maximum notched Izod impact strength was found for weight-average PCL droplet diameter between 0.3 and 0.5 μm.
“For the blends with the high PLA crystallinity (46-48%), the maximum of the impact strength was found for d w between 0.3 and 0.5 µm.”
From Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review (2019) · cites this paper as Bai et al., 2013
The crystallinity of PLA in its blends processed by common procedures tends to be very low, typically lower than 10%.
“Consequently, the crystallinity of PLA in its blends processed by common procedures tends to be very low, typically lower than 10% (Bai et al., 2012(Bai et al., , 2013;;Ostafinska et al., 2015Ostafinska et al., , 2017)).”
From Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review (2019) · cites this paper as Bai et al., 2013
For PLA/PCL (80/20) blends with low PLA crystallinity (6.5-9.5%), the maximum notched Izod impact strength was achieved for weight-average PCL droplet diameter between 0.7 and 1.1 μm.
“For the blends with the low PLA crystallinity (6.5-9.5%), the maximum impact strength was achieved for d w between 0.7 and 1.1 µm.”
From Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review (2019) · cites this paper as Bai et al., 2013
The maximum impact strength achieved for the blends with high PLA crystallinity was almost two times higher than that of the blends with low PLA crystallinity.
“It should be mentioned that the maximum value of the impact strength achieved for the blends with the high PLA crystallinity was almost two times higher than that of the blends with a low PLA crystallinity.”
From Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review (2019) · cites this paper as Bai et al., 2013
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References 51 · Cited by 153
- Authors
- Bai, H., Huang, C., Xiu, H., Gao, Y., Zhang, Q., & Fu, Q.
- Affiliations
- Sichuan University (CN)
- Corresponding author
- Fu, Qiang
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2013-08
- Volume
- 54
- Issue
- 19
- Pages
- 5257-5266
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2046055005
- Cited by
- 153
- References
- 51
- Citations by year
- 2026: 6 · 2025: 5 · 2024: 17 · 2023: 18 · 2022: 17 · 2021: 12 · 2020: 16 · 2019: 9 · 2018: 12 · 2017: 15 · 2016: 7 · 2015: 14 · 2014: 5
- FWCI
- 6.26
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Funders
- National Natural Science Foundation of China (50903048, 51121001)
- China Postdoctoral Science Foundation (2013M530399)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Foaming and Composites
- Keywords
- poly(L-lactic acid), polycaprolactone, impact toughening, polymer blends, matrix crystallization, nucleating agents, shear yielding, crazing, heat resistance, biodegradable polymers
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