The DOI matches its Crossref record; 162 of the 162 references it cites were found in a registry or an index.
Alkaline-stable anion exchange membranes: A review of synthetic approaches
Open accessAbstract
Abstract In honor of the 100th anniversary of Staudinger’s “Polymer Hypothesis”, we write this trend review to describe some key developments in the synthesis of cationic polymers. Cationic polymers provided early evidence in support of the Polymer Hypothesis and have been recognized for their tremendous potential in various sub-disciplines of chemistry and biology. This article is focused on a specific class of cationic polymers that conduct hydroxide anions, namely alkaline anion exchange membranes (AAEMs). These polymers are essential components in anion exchange membrane fuel cell (AEMFC) energy conversion devices that can operate with zero-emission fuels (H2 and O2) and do not require precious metals (e.g. platinum) as electrocatalysts for oxygen reduction. One of the critical considerations for AAEMs is their long-term stability to alkaline media, and as such, a wide range of polymer backbones and appended cations have been evaluated as potential constructs for this purpose. Herein, an overview of the different classes of cations is presented, along with a description of the typical synthetic methods for the preparation of AAEMs. By organizing the review according to the synthetic strategies, we hope to inspire the design and preparation of new cationic materials that are suitable for AEMFCs.
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Cites
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Anion exchange membranes for alkaline fuel cells: A review
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Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Self-citationTay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Anion exchange polyelectrolytes for membranes and ionomers
Chen, N., & Lee, Y. M. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101345 · Cited by 445
Recent trends in carbon support for improved performance of alkaline fuel cells
Fashedemi, O. O., Bello, A., Adebusuyi, T., & Bindir, S. (2022) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2022.101132 · Cited by 35
Metadata
- Authors
- You, W., Noonan, K. J. T., & Coates, G. W.
- Venue
- Progress in Polymer Science
- Publisher
- Elsevier BV
- Published
- 2020-01
- Volume
- 100
- Pages
- 101177
- ISSN
- 0079-6700 (ISSN-L)
- OpenAlex
- W2982867372
- Cited by
- 389
- References
- 162
- FWCI
- 15.33
- Type
- journal article
- Language
- en
- Open access
- bronze
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