The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Recent innovations in analytical methods for the qualitative and quantitative assessment of lignin
Open accessAbstract
As the attraction of creating biofuels and bio-based chemicals from lignocellulosic biomass has increased, researchers have been challenged with developing a better understanding of lignin structure, quantity and potential uses. Lignin has frequently been considered a waste-product from the deconstruction of plant cell walls, in attempts to isolate polysaccharides that can be hydrolyzed and fermented into fuel or other valuable commodities. In order to develop useful applications for lignin, accurate analytical instrumentation and methodologies are required to qualitatively and quantitatively assess, for example, what the structure of lignin looks like or how much lignin comprises a specific feedstock׳s cellular composition . During the past decade, various diverse strategies have been employed to elucidate the structure and composition of lignin. These techniques include using two-dimensional nuclear magnetic resonance to resolve overlapping spectral data, measuring biomass with vibrational spectroscopy to enable modeling of lignin content or monomeric ratios, methods to probe and quantify the linkages between lignin and polysaccharides , or refinements of established methods to provide higher throughput analyses , less use of consumables, etc. This review seeks to provide a comprehensive overview of many of the advancements achieved in evaluating key lignin attributes. Emphasis is placed on research endeavored in the last decade.
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Cites
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The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
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Theoretical Study of the Remarkably Diverse Linkages in Lignin
Parthasarathi, R., Romero, R. A., Redondo, A., & Gnanakaran, S. (2011) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201201q · Cited by 433
Self-citationBeste, A., & Buchanan, A. C. (2009) · The Journal of Organic Chemistry · doi:10.1021/jo9001307 · Cited by 168
Hu, J., Xiao, R., Shen, D., & Zhang, H. (2013) · Bioresource Technology · doi:10.1016/j.biortech.2012.10.148 · Cited by 117
Free-Radical Analysis on Thermochemical Transformation of Lignin to Phenolic Compounds
Hu, J., Shen, D., Xiao, R., Wu, S., & Zhang, H. (2013) · Energy & Fuels · doi:10.1021/ef3016602 · Cited by 116
Lupoi, J. S., & Smith, E. A. (2012) · Applied Spectroscopy · doi:10.1366/12-06621 · Cited by 59
Self-citationHoltman, K. M., Chang, H., & Kadla, J. F. (2007) · Journal of Wood Chemistry and Technology · doi:10.1080/02773810701700828 · Cited by 43 · cited 1×
“GPC also aided in evaluating the MW of lignin isolated from: binderless boards produced from thermomechanical pulp [134], milled pine, MWL, and residual enzyme lignin [150], industrial black liquor [61], and the effect of a dilute phosphoric acid/steam explosion pretreatment on sugarcane bagasse lignin [167].”
Background
Cited by
Guidelines for performing lignin-first biorefining
Abu-Omar, M. M., Barta, K., Beckham, G. T., Luterbacher, J. S., Ralph, J., Rinaldi, R., Román-Leshkov, Y., Samec, J. S. M., Sels, B. F., & Wang, F. (2021) · Energy & Environmental Science · doi:10.1039/d0ee02870c · Cited by 913
Constant, S., Wienk, H. L. J., Frissen, A. E., Peinder, P. D., Boelens, R., van Es, D. S., Grisel, R. J. H., Weckhuysen, B. M., Huijgen, W. J. J., Gosselink, R. J. A., et al. (2016) · Green Chemistry · doi:10.1039/c5gc03043a · Cited by 893
Dessbesell, L., Paleologou, M., Leitch, M., Pulkki, R., & Xu, C. (. (2020) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2020.109768 · Cited by 508
Collins, M. N., Nechifor, M., Tanasă, F., Zănoagă, M., McLoughlin, A., Stróżyk, M. A., Culebras, M., & Teacă, C.-A. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2019.03.069 · Cited by 486
Phenol-derived products from fast pyrolysis of organosolv lignin
Soongprasit, K., Sricharoenchaikul, V., & Atong, D. (2020) · Energy Reports · doi:10.1016/j.egyr.2020.08.040 · Cited by 55
Metadata
- Authors
- Lupoi, J. S., Singh, S., Parthasarathi, R., Simmons, B. A., & Henry, R. J.
- Venue
- Renewable and Sustainable Energy Reviews
- Publisher
- Elsevier BV
- Published
- 2015-09
- Volume
- 49
- Pages
- 871-906
- ISSN
- 1364-0321 (ISSN-L)
- OpenAlex
- W1812516225
- Cited by
- 390
- References
- 8
- FWCI
- 15.88
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Lupoi, J. S., Singh, S., Parthasarathi, R., Simmons, B. A., & Henry, R. J. (2015). Recent innovations in analytical methods for the qualitative and quantitative assessment of lignin. Renewable and Sustainable Energy Reviews. https://doi.org/10.1016/j.rser.2015.04.091
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
