CoChat
Sign Up
Cited by 201Mineralogy and Gemology StudiesSpectroscopy Techniques in Biomedical and Chemical ResearchCultural Heritage Materials Analysis

The DOI matches its Crossref record.

A Raman spectroscopic comparison of calcite and dolomite

Open access
Sun, Junmin, Wu, Zeguang, Cheng, Hongfei, Zhang, Zhanjun, Frost, Ray L.·2014·Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
DOI 10.1016/j.saa.2013.08.014
Open this paper in CoChat — free accountOpen PDF

Abstract

Raman spectroscopy was used to characterize and differentiate the two minerals calcite and dolomite and the bands related to the mineral structure. The (CO3)(2-) group is characterized by four prominent Raman vibrational modes: (a) the symmetric stretching, (b) the asymmetric deformation, (c) asymmetric stretching and (d) symmetric deformation. These vibrational modes of the calcite and dolomite were observed at 1440, 1088, 715 and 278 cm(-1). The significant differences between the minerals calcite and dolomite are observed by Raman spectroscopy. Calcite shows the typical bands observed at 1361, 1047, 715 and 157 cm(-1), and the special bands at 1393, 1098, 1069, 1019, 299, 258 and 176 cm(-1) for dolomite are observed. The difference is explained on the basis of the structure variation of the two minerals. Calcite has a trigonal structure with two molecules per unit cell, and dolomite has a hexagonal structure. This is more likely to cause the splitting and distorting of the carbonate groups. Another cause for the difference is the cation substituting for Mg in the dolomite mineral.

Overview

Integrity signals

Registry

Crossref · 10.1016/j.saa.2013.08.014

Cites

Statistics

Recomputing p-values needs the paper’s full text.

Verification

Claims the paper makes

We couldn’t retrieve this paper’s full text, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Citations

Cites

No references could be resolved yet.

Research works printed but not linked: 18

  1. Gunasekaran, 2007, J. Raman Spectrosc., 38, 846, 10.1002/jrs.1718 · DOI
  2. Baltrusaitis, 2009, Surf. Sci., 603, L99, 10.1016/j.susc.2009.06.021 · DOI
  3. Gunasekaran, 2006, J. Raman Spectrosc., 37, 892, 10.1002/jrs.1518 · DOI
  4. Vavouraki, 2008, Chem. Geol., 253, 243, 10.1016/j.chemgeo.2008.05.013 · DOI
  5. Frost, 2008, J. Raman Spectrosc., 39, 108, 10.1002/jrs.1835 · DOI
  6. Frost, 2004, J. Raman Spectrosc., 35, 299, 10.1002/jrs.1150 · DOI
  7. Frost, 2004, Thermochim. Acta, 419, 119, 10.1016/j.tca.2004.02.006 · DOI
  8. Frost, 2004, Thermochim. Acta, 419, 109, 10.1016/j.tca.2004.02.002 · DOI
  9. Palmer, 2007, J. Raman Spectrosc., 38, 1602, 10.1002/jrs.1820 · DOI
  10. Frost, 2007, J. Raman Spectrosc., 38, 1516, 10.1002/jrs.1806 · DOI
  11. Frost, 2008, J. Raman Spectrosc., 39, 374, 10.1002/jrs.1829 · DOI
  12. Frost, 2009, J. Raman Spectrosc., 40, 360, 10.1002/jrs.2110 · DOI
  13. Frost, 2009, J. Raman Spectrosc., 40, 855, 10.1002/jrs.2152 · DOI
  14. Frost, 2009, J. Raman Spectrosc., 40, 1096, 10.1002/jrs.2174 · DOI
  15. Frost, 2007, J. Raman Spectrosc., 38, 873, 10.1002/jrs.1733 · DOI
  16. Gunasekaran, 2007, Spectrochim. Acta A, 68, 656, 10.1016/j.saa.2006.12.043 · DOI
  17. Gunasekaran, 2008, Spectrochim. Acta A, 69, 1246, 10.1016/j.saa.2007.06.036 · DOI
  18. Tlili, 2002, J. Raman Spectrosc., 33, 10, 10.1002/jrs.806 · DOI

Cited by

Sorted by citations

Metadata

Authors
Sun, J., Wu, Z., Cheng, H., Zhang, Z., & Frost, R. L.
Affiliations
  • China University of Mining and Technology - Beijing (CN)
  • Queensland University of Technology (AU)
Corresponding author
  • Cheng, Hongfei
  • Frost, Ray L.
ORCID
Venue
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Publisher
Elsevier BV
Published
2014-01
Volume
117
Pages
158-162
ISSN
1386-1425 (ISSN-L)
DOI
10.1016/j.saa.2013.08.014
OpenAlex
W2006321893
Cited by
201
References
0
Citations by year
2026: 26 · 2025: 27 · 2024: 19 · 2023: 26 · 2022: 22 · 2021: 21 · 2020: 11 · 2019: 7 · 2018: 16 · 2017: 10 · 2016: 8 · 2015: 8
FWCI
6.69
Type
journal article
Language
en
Open access
Licence
Locations
  • Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy (publishedVersion)
  • PubMed (publishedVersion)
  • QUT ePrints (Queensland University of Technology) (submittedVersion, cc-by-nc-nd)
Topics
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
  • Social Sciences › Arts and Humanities › Archeology (arts and humanities) › Cultural Heritage Materials Analysis
Keywords
calcite, dolomite, carbonate minerals, Raman modes, magnesium substitution, mineral identification
MeSH terms
Calcium Carbonate, Magnesium, Spectrophotometry, Infrared, Spectrum Analysis, Raman, Vibration, Molecular Structure

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review