A systematic study of the kinetics of lignin pyrolysis
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Reported literature apparent activation energies include cellulose 180-250 kJ/mol, lignin 50-360 kJ/mol and 75-230 kJ/mol, spruce hemicellulose 218-230 kJ/mol, xylan 178 kJ/mol, and softwood hemicellulose 158-186 kJ/mol.
“cellulose: 180–250 kJ/mol (single stepmodel- fitting or isoconversionalmethods) [11], lignin: 50–360 kJ/mol (single or several heating rate data) [44] and 75–230 kJ/mol (isoconversional method) [41]”
From Pyrolysis of kraft pulp and black liquor precipitates derived from spruce: Thermal and kinetic analysis (2016) · cites this paper as [44]
The wide scatter in lignin kinetic data is partly related to the method used to derive kinetics: 50-80 kJ/mol using single heating rate data and 50-360 kJ/mol from several heating rate data.
“The wide scatter in the data for lignin seems to be partly related to the method used to derive the kinetics: between 50 and 80 kJ/mol using single heating rate data and 50–360 kJ/mol from several heating rate data [44].”
From Pyrolysis of kraft pulp and black liquor precipitates derived from spruce: Thermal and kinetic analysis (2016) · cites this paper as [44]
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References 38 · Cited by 352
- Authors
- Jiang, G., Nowakowski, D. J., & Bridgwater, A. V.
- Affiliations
- Aston University (GB)
- Corresponding author
- Jiang, Guozhan
- Venue
- Thermochimica Acta
- Publisher
- Elsevier BV
- Published
- 2010-01
- Volume
- 498
- Issue
- 1-2
- Pages
- 61-66
- ISSN
- 0040-6031 (ISSN-L)
- OpenAlex
- W1977002322
- Cited by
- 352
- References
- 38
- Citations by year
- 2026: 8 · 2025: 15 · 2024: 11 · 2023: 15 · 2022: 25 · 2021: 25 · 2020: 29 · 2019: 24 · 2018: 17 · 2017: 32 · 2016: 34 · 2015: 27 · 2014: 32 · 2013: 25 · 2012: 13
- FWCI
- 5.32
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Thermochimica Acta (publishedVersion)
- Funders
- Engineering and Physical Sciences Research Council (EP/E039995/1)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Physical Sciences › Engineering › Biomedical Engineering › Lignin and Wood Chemistry
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- lignin pyrolysis, pyrolysis kinetics, activation energy, reaction order, pre-exponential factor, alkali lignin, hydrolytic lignin, organosolv lignin, Klason lignin, plant species effects
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