The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Mechanisms of Nickel-Catalyzed Cross-Coupling Reactions
Abstract
Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space of accessible structures and enabled new synthetic disconnections. The unique properties of Ni catalysts facilitate the activation of traditionally inert substrates, tolerate alkyl coupling partners that undergo decomposition via β-hydride (β-H) elimination with Pd, and enable stereoconvergent cross-couplings. The radical pathways accessed by Ni catalysts have been merged with photoredox and electrochemical catalysis to achieve new reactivity. The growing utility of Ni catalysis is, in no small part, due to advances in our fundamental understanding of the properties of Ni catalysts and the mechanisms by which the reactions occur. This review highlights recent important contributions to the field with an emphasis on studies that have afforded mechanistic insight.
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Cites
Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
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A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents
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Cited by
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Liu, B., Romine, A. M., Rubel, C. Z., Engle, K. M., & Shi, B.-F. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00519 · Cited by 538
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Late-stage difluoromethylation: concepts, developments and perspective
Sap, J. B. I., Meyer, C. F., Straathof, N. J. W., Iwumene, N., am Ende, C. W., Trabanco, A. A., & Gouverneur, V. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00360g · Cited by 432
Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis
Ehehalt, L. E., Beleh, O. M., Priest, I. C., Mouat, J. M., Olszewski, A. K., Ahern, B. N., Cruz, A. R., Chi, B. K., Castro, A. J., Kang, K., et al. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.4c00524 · Cited by 312
Metadata
- Authors
- Diccianni, J. B., & Diao, T.
- Venue
- Trends in Chemistry
- Publisher
- Elsevier BV
- Published
- 2019-12
- Volume
- 1
- Issue
- 9
- Pages
- 830-844
- ISSN
- 2589-5974 (ISSN-L)
- OpenAlex
- W2973096734
- Cited by
- 584
- References
- 35
- FWCI
- 2.76
- Type
- journal article
- Language
- en
- Open access
- closed
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