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Sonolytic degradation of endocrine disrupting chemical 4-cumylphenol in water
Abstract
The sonolytic degradation of endocrine disrupting compound 4-cumylphenol (4-CyP) in aqueous solution was investigated. The influence of operating parameters for sonication process such as 4-CyP initial concentration, frequency, power, pH, temperature and saturating gas was examined. The extent of degradation was inversely proportional to the initial substrate concentration. The rate of 4-CyP degradation was frequency dependent. The degradation rate increased proportionally with increasing ultrasonic power from 20 to 100 W and temperature in the range of 20-50°C. The most favorable degradation pH was acidic media. Destruction in the presence of saturating gas follows the order: argon>air>nitrogen. The 4-CyP degradation was inhibited in the presence of nitrogen gas owing to the free radical scavenging effect in vapor phase within the bubbles of cavitation. The ultrasonic degradation of 4-CyP was clearly promoted in the presence of bromide anions and the promoting effect on degradation increased with increasing bromide concentration. At low 4-CyP concentration (0.05 mg L(-1)), bicarbonate ion drastically enhanced the rate of 4-CyP degradation. Experiments conducted using pure and natural water demonstrated that the sonolytic treatment was more efficient in the natural water compared to pure water.
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“Similar results, i.e., an enhancement in the degradation at lower pollutant concentrations, was reported for bisphenol S, N,N-Diethyl-meta-toluamide (DEET), 4-cumylphenol, etc. [104-106].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [106]
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Self-citationAhmedchekkat, F., Chiha, M., Bsoul, A. A., & Hailat, M. (2021) · Desalination and Water Treatment · doi:10.5004/dwt.2021.26892 · Cited by 2
Self-citationWu, B., Song, C., Nan, S., Sun, B., Ma, H., & Guo, Y. (2025) · Agriculture · doi:10.3390/agriculture15101085 · Cited by 2
Cesaro, A., & Belgiorno, V. (2015) · The Open Biotechnology Journal · doi:10.2174/1874070720151112e012 · Cited by 2
Anggoro, D. D., Dewi, I. K., Buchori, L., & Prasetyaningrum, A. (2023) · IIUM Engineering Journal · doi:10.31436/iiumej.v24i2.2717 · Cited by 1
Elimination of Benzophenone-1 in Water by High-Frequency Ultrasound
Vega, L. P., Zúñiga‐Benítez, H., & Peñuela, G. A. (2021) · Water Air & Soil Pollution · doi:10.1007/s11270-021-05443-2 · Cited by 1
Metadata
- Authors
- Chiha, M., Hamdaoui, O., Baup, S., & Gondrexon, N.
- Affiliations
- Badji Mokhtar-Annaba University (DZ)
- Laboratoire d’Electrochimie et de Physico-chimie des Matériaux et des Interfaces (FR)
- Corresponding author
- Hamdaoui, Oualid
- Venue
- Ultrasonics Sonochemistry
- Publisher
- Elsevier BV
- Published
- 2011-09
- Volume
- 18
- Issue
- 5
- Pages
- 943-950
- ISSN
- 1350-4177 (ISSN-L)
- OpenAlex
- W2088363324
- Cited by
- 104
- References
- 45
- Citations by year
- 2026: 3 · 2025: 7 · 2024: 6 · 2023: 9 · 2022: 6 · 2021: 14 · 2020: 8 · 2019: 4 · 2018: 10 · 2017: 4 · 2016: 8 · 2015: 8 · 2014: 5 · 2013: 7 · 2012: 3
- FWCI
- 1.88
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Ultrasonics Sonochemistry (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- Ministry of Higher Education and Scientific Research of Algeria
- Topics
- Physical Sciences › Physics and Astronomy › Acoustics and Ultrasonics › Ultrasound and Cavitation Phenomena
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Engineering › Biomedical Engineering › Ultrasound and Hyperthermia Applications
- Keywords
- endocrine disruptors, ultrasonic degradation, cavitation, free radical scavenging, bromide, bicarbonate, pH effect, ultrasonic power, ultrasonic frequency, natural waters, wastewater treatment
- MeSH terms
- Phenols, Radiation Dosage, Sonication, Water, Water Pollutants, Chemical, Water Purification, Endocrine Disruptors
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