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Facile sonochemical synthesis of perovskite-type SrTiO3 nanocubes with reduced graphene oxide nanocatalyst for an enhanced electrochemical detection of α-amino acid (tryptophan)
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In this paper, perovskite-type SrTiO3 nanocubes decorated reduced graphene oxide is synthesized by sonochemical method. The as-synthesized SrTiO3@RGO nanocomposite was confirmed by XRD, TEM, SEM, elemental mapping and electrochemical technique. Furthermore, surface morphological and X-ray diffraction studies revealed the formation and high loading of SrTiO3 nanocubes on reduced graphene oxide matrix. The SrTiO3@RGO nanocomposite modified electrode shows an excellent electrochemical detection towards of amino acid (tryptophan). The developed sensor was showed a wide linear range from 30 nM to 917.3 µM and detection limit is 7.15 nM. Furthermore, the sensitivity was calculated to be 9.11 µA µM−1 cm2. In addition, the proposed modified sensor is exhibited good selectivity, stability, reproducibility and repeatability. The SrTiO3@RGO catalyst modified electrode was successfully applied to tryptophan analysis in biological samples.
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Govindasamy et al. synthesized SrTiO3 nanotubes modified with rGO, achieving a detection limit of 7.15 nM for tryptophan.
“Govindasamy et al. [188] synthesized SrTiO 3 nanotubes modified with rGO, achieving a detection limit of 7.15 nM for tryptophan (Figure 12D).”
From Design Strategies and Emerging Applications of Perovskite-Based Sensors (2025) · cites this paper as [188]
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Research works printed but not linked: 57
- Naganathan, 2018, Ce doped ZnO/f-MWCNT moss ball like nanocomposite: a strategy for high responsive current detection of L-tryptophan, Microchim. Acta, 185, 96, 10.1007/s00604-017-2641-1 · DOI
- Sun, 2018, Electrodeposition synthesis of a NiO/CNT/PEDOT composite for simultaneous detection of dopamine, serotonin, and tryptophan, Sens. Actuators B: Chem., 259, 433, 10.1016/j.snb.2017.12.037 · DOI
- Beuning, 2018, Measurement of interpeptidic Cu (II) exchange rate constants by static fluorescence quenching of tryptophan, Inorg. Chem., 57, 4791, 10.1021/acs.inorgchem.8b00182 · DOI
- Kwon, 2018, Tunable plasmonic cavity for label-free detection of small molecules, ACS Appl. Mater. Interfaces, 10, 13226, 10.1021/acsami.8b01550 · DOI
- Szunerits, 2010, Preparation of boron-doped diamond nanowires and their application for sensitive electrochemical detection of tryptophan, Electrochem. Commun., 12, 438, 10.1016/j.elecom.2010.01.014 · DOI
- Govindasamy, 2017, Methyl parathion detection in vegetables and fruits using silver@ graphene nanoribbons nanocomposite modified screen printed electrode, Sci. Rep., 7, 46471, 10.1038/srep46471 · DOI
- Govindasamy, 2016, MoS2 flowers grown on graphene/carbon nanotubes: a versatile substrate for electrochemical determination of hydrogen peroxide, Int. J. Electrochem. Sci., 11, 2954, 10.20964/110402954 · DOI
- Wang, 2013, Simultaneous electrochemical detection of tryptophan and tyrosine using boron-doped diamond and diamond nanowire electrodes, Electrochem. Commun., 35, 84, 10.1016/j.elecom.2013.08.010 · DOI
- Jin, 2003, Simultaneous determination of tryptophan and glutathione in individual rat hepatocytes by capillary zone electrophoresis with electrochemical detection at a carbon fiber bundle− Au/Hg dual electrode, Anal. Chem., 75, 3859, 10.1021/ac0207022 · DOI
- Sagara, 1988, Determination of plasma 5-hydroxytryptophan, 5-hydorxytryptamine, 5-hydorxyindoleacetic acid, tryptophan and melatonin by high-performance liquid chromatography with electrochemical detection, J. Chromatogr. B Biomed. Sci. Appl., 431, 170, 10.1016/S0378-4347(00)83081-9 · DOI
- Li, 2018, Facile synthesis of Pd− Cu@ Cu2O/N-RGO hybrid and its application for electrochemical detection of tryptophan, Electrochim. Acta, 260, 526, 10.1016/j.electacta.2017.12.125 · DOI
- Mergu, 2018, Highly selective naphthalimide-benzothiazole hybrid-based colorimetric and turn on fluorescent chemosensor for cyanide and tryptophan detection in aqueous media, Sens. Actuators B: Chem., 10.1016/j.snb.2018.05.165 · DOI
- Mohammadi, 2018, Voltammetric determination of tryptophan using a carbon paste electrode modified with magnesium core shell nanocomposite and ionic liquids, Anal. Bioanal. Chem. Res., 5, 55
- Du, 2018, Simultaneous determination of tryptophan, kynurenine, kynurenic acid and two monoamines in rat plasma by HPLC-ECD/DAD, J. Pharm. Biomed. Anal., 158, 8, 10.1016/j.jpba.2018.05.032 · DOI
- Karimi, 2018, Sens. Actuators B: Chem., 257, 1134, 10.1016/j.snb.2017.11.014 · DOI
- Tajyani, 2018, A new sensing platform based on magnetic Fe3O4@ NiO core/shell nanoparticles modified carbon paste electrode for simultaneous voltammetric determination of Quercetin and Tryptophan, J. Electroanal. Chem., 808, 50, 10.1016/j.jelechem.2017.11.010 · DOI
- Özcan, 2018, Preparation of a disposable and low-cost electrochemical sensor for propham detection based on over-oxidized poly (thiophene) modified pencil graphite electrode, Talanta, 187, 125, 10.1016/j.talanta.2018.05.018 · DOI
- Govindasamy, 2017, Molybdenum disulfide nanosheets coated multiwalled carbon nanotubes composite for highly sensitive determination of chloramphenicol in food samples milk, honey and powdered milk, J. Colloids Interface Sci., 485, 129, 10.1016/j.jcis.2016.09.029 · DOI
- Govindasamy, 2016, Simultaneous determination of dopamine and uric acid in the presence of high ascorbic acid concentration using cetyltrimethylammonium bromide–polyaniline/activated charcoal composite, RSC Adv., 6, 100605, 10.1039/C6RA18740D · DOI
- Mani, 2017, Core-shell heterostructured multiwalled carbon nanotubes@ reduced graphene oxide nanoribbons/chitosan, a robust nanobiocomposite for enzymatic biosensing of hydrogen peroxide and nitrite, Sci. Rep., 7, 11910, 10.1038/s41598-017-12050-x · DOI
- Ohta, 2008, Recent progress in oxide thermoelectric materials: p-type Ca3Co4O9 and n-type SrTiO3−, Inorg. Chem., 47, 8429, 10.1021/ic800644x · DOI
- Onishi, 2008, The hybrid-DFT study on bandgap estimation for the perovskite-type titanium oxide of SrTiO3, Int. J. Quantum Chem., 108, 2856, 10.1002/qua.21869 · DOI
- Higuchi, 1998, Electronic structure of p-type SrTiO3 by photoemission spectroscopy, Phys. Rev. B, 57, 6978, 10.1103/PhysRevB.57.6978 · DOI
- Chen, 2018, Hierarchically structured CuFe2O4 ND@ RGO composite for the detection of oxidative stress biomarker in biological fluids, Inorg. Chem. Front., 5, 944, 10.1039/C7QI00799J · DOI
- Wang, 2006, Photophysical and photocatalytic properties of SrTiO3 doped with Cr cations on different sites, J. Phys. Chem. B, 110, 15824, 10.1021/jp062487p · DOI
- Escudero, 2009, Development of anode material based on La-substituted SrTiO3 perovskites doped with manganese and/or gallium for SOFC, J. Power Sources, 192, 43, 10.1016/j.jpowsour.2008.11.132 · DOI
- Manavalan, 2018, Reduced graphene oxide supported raspberry-like SrWO4 for sensitive detection of catechol in green tea and drinking water samples, J. Taiwan Inst. Chem. Eng., 10.1016/j.jtice.2018.05.001 · DOI
- Rajaji, 2018, Microwave-assisted synthesis of Bi2WO6 flowers decorated graphene nanoribbon composite for electrocatalytic sensing of hazardous dihydroxybenzene isomers, Compos. Part B Eng., 152, 220, 10.1016/j.compositesb.2018.07.003 · DOI
- Govindasamy, 2017, Graphene oxide nanoribbons film modified screen-printed carbon electrode for real-time detection of methyl parathion in food samples, J. Electrochem. Soc., 164, B403, 10.1149/2.0371709jes · DOI
- Rajaji, 2019, Graphene oxide encapsulated 3D porous chalcopyrite (CuFeS2) nanocomposite as an emerging electrocatalyst for agro-hazardous (methyl paraoxon) detection in vegetables, Compos. Part B: Eng., 160, 268, 10.1016/j.compositesb.2018.10.042 · DOI
- Ahmad, 2016, Preparation of SrTiO3 perovskite decorated rGO and electrochemical detection of nitroaromatics, Electrochim. Acta, 215, 435, 10.1016/j.electacta.2016.08.123 · DOI
- Kumar, 2012, Probing surface and bulk electrochemical processes on the LaAlO3–SrTiO3 interface, ACS Nano, 6, 3841, 10.1021/nn204960c · DOI
- Sahner, 2006, HC-sensor for exhaust gases based on semiconducting doped SrTiO3 for On-Board Diagnosis, Sens. Actuators B: Chem., 114, 861, 10.1016/j.snb.2005.08.005 · DOI
- Matsui, 2018, Highly stable plasmon induced hot hole transfer into silicon via a SrTiO3 passivation interface, Adv. Funct. Mater., 28, 1705829, 10.1002/adfm.201705829 · DOI
- Dua, 2010, All-organic vapor sensor using inkjet-printed reduced graphene oxide, Angew. Chem., 122, 2200, 10.1002/ange.200905089 · DOI
- Mani, 2013, Direct electrochemistry of glucose oxidase at electrochemically reduced graphene oxide-multiwalled carbon nanotubes hybrid material modified electrode for glucose biosensor, Biosens. Bioelectron., 41, 309, 10.1016/j.bios.2012.08.045 · DOI
- Mani, 2012, Highly selective amperometric nitrite sensor based on chemically reduced graphene oxide modified electrode, Electrochem. Commun., 17, 75, 10.1016/j.elecom.2012.02.009 · DOI
- Mani, 2014, Direct electrochemistry of myoglobin at reduced graphene oxide-multiwalled carbon nanotubes-platinum nanoparticles nanocomposite and biosensing towards hydrogen peroxide and nitrite, Biosens. Bioelectron., 53, 420, 10.1016/j.bios.2013.09.075 · DOI
- Ponnusamy, 2014, Rapid microwave assisted synthesis of graphene nanosheets/polyethyleneimine/gold nanoparticle composite and its application to the selective electrochemical determination of dopamine, Talanta, 120, 148, 10.1016/j.talanta.2013.12.003 · DOI
- Devasenathipathy, 2014, Highly stable and sensitive amperometric sensor for the determination of trace level hydrazine at cross linked pectin stabilized gold nanoparticles decorated graphene nanosheets, Electrochim. Acta, 135, 260, 10.1016/j.electacta.2014.05.002 · DOI
- Govindasamy, 2018, Facile synthesis of copper sulfide decorated reduced graphene oxide nanocomposite for high sensitive detection of toxic antibiotic in milk, Ultrason. Sonochem.
- Ashiri, 2015, Sonochemical synthesis of SrTiO3 nanocrystals at low temperature, Int. J. Appl. Ceram. Technol., 12, E202, 10.1111/ijac.12315 · DOI
- Mani, 2017, Determination of folic acid using graphene/molybdenum disulfide nanosheets/gold nanoparticles ternary composite, Int. J. Electrochem. Sci., 12, 10.20964/2017.01.35 · DOI
- Govindasamy, 2017, Reduced graphene oxide supported cobalt Bipyridyl complex for sensitive detection of methyl parathion in fruits and vegetables, Electroanalysis, 29, 1950, 10.1002/elan.201700186 · DOI
- Govindasamy, 2017, Highly sensitive determination of non-steroidal anti-inflammatory drug nimesulide using electrochemically reduced graphene oxide nanoribbons, RSC Adv., 7, 33043, 10.1039/C7RA02844J · DOI
- Govindasamy, 2018, Determination of oxidative stress biomarker 3-nitro-L-tyrosine using CdWO4 nanodots decorated reduced graphene oxide, Sens. Actuators B: Chem., 272, 274, 10.1016/j.snb.2018.05.138 · DOI
- Chen, 2018, Advanced fuel cell based on perovskite La–SrTiO3 semiconductor as the electrolyte with superoxide-ion conduction, ACS Appl. Mater. Interfaces, 10, 33179, 10.1021/acsami.8b10087 · DOI
- Liu, 2008, Combustion synthesis and characterization of perovskite SrTiO3 nanopowders, J. Alloy. Compd., 457, L12, 10.1016/j.jallcom.2007.03.080 · DOI
- Fan, 2011, Electrochemistry and voltammetric determination of L-tryptophan and L-tyrosine using a glassy carbon electrode modified with a Nafion/TiO2-graphene composite film, Microchim. Acta, 173, 241, 10.1007/s00604-011-0556-9 · DOI
- Haldorai, 2017, Electrochemical determination of tryptophan using a glassy carbon electrode modified with flower-like structured nanocomposite consisting of reduced graphene oxide and SnO2, Sens. Actuators B: Chem., 239, 1221, 10.1016/j.snb.2016.09.119 · DOI
- Mao, 2012, Sensitive electrochemical sensor of tryptophan based on Ag@C core–shell nanocomposite modified glassy carbon electrode, Anal. Chim. Acta, 738, 35, 10.1016/j.aca.2012.06.008 · DOI
- Kooshki, 2011, Second-order data obtained from differential pulse voltammetry: determination of tryptophan at a gold nanoparticles decorated multiwalled carbon nanotube modified glassy carbon electrode, Electrochim. Acta, 56, 8618, 10.1016/j.electacta.2011.07.049 · DOI
- Ghoreishi, 2012, Electrochemical determination of tryptophan, uric acid and ascorbic acid at a gold nanoparticles modified carbon paste electrode, Anal. Methods, 4, 2447, 10.1039/c2ay00017b · DOI
- Özcan, 2012, A novel approach for the selective determination of tryptophan in blood serum in the presence of tyrosine based on the electrochemical reduction of oxidation product of tryptophan formed in situ on graphite electrode, Biosens. Bioelectron., 31, 26, 10.1016/j.bios.2011.09.048 · DOI
- Li, 2010, Electrochemical investigation of tryptophan at gold nanoparticles modified electrode in the presence of sodium dodecylbenzene sulfonate, Colloids Surf. B: Biointerfaces, 76, 340, 10.1016/j.colsurfb.2009.11.017 · DOI
- Shahrokhian, 2007, Carbon paste electrode incorporating multi-walled carbon nanotube/cobalt salophen for sensitive voltammetric determination of tryptophan, Sens. Actuators B: Chem., 123, 942, 10.1016/j.snb.2006.10.053 · DOI
- Deng, 2014, Acetylene black paste electrode modified with graphene as the voltammetric sensor for selective determination of tryptophan in the presence of high concentrations of tyrosine, Mater. Sci. Eng. C, 35, 54, 10.1016/j.msec.2013.10.019 · DOI
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Metadata
- Authors
- Govindasamy, M., Wang, S.-F., Pan, W. C., Subramanian, B., Ramalingam, R. J., & Al-lohedan, H.
- Affiliations
- National Taipei University of Technology (TW)
- Corresponding author
- Wang, Sea-Fue
- Venue
- Ultrasonics Sonochemistry
- Publisher
- Elsevier BV
- Published
- 2019-09
- Volume
- 56
- Pages
- 193-199
- ISSN
- 1350-4177 (ISSN-L)
- OpenAlex
- W2939565493
- Cited by
- 112
- References
- 0
- Citations by year
- 2026: 1 · 2025: 12 · 2024: 5 · 2023: 14 · 2022: 17 · 2021: 13 · 2020: 34 · 2019: 16
- FWCI
- 7.19
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Ultrasonics Sonochemistry (publishedVersion, cc-by-nc-nd)
- PubMed (publishedVersion)
- Funders
- National Taipei University of Technology
- King Saud University
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Electrochemical sensors and biosensors
- Physical Sciences › Chemistry › Electrochemistry › Electrochemical Analysis and Applications
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- perovskite, reduced graphene oxide, nanocomposites, electrochemical sensor, tryptophan detection, amino acid sensing, modified electrode, sonochemical synthesis, biological specimen
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