The acid-promoted reaction of ethyl linoleate with nitrite. New insights from 15N-labelling and peculiar reactivity of a model skipped diene
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Protonation of NO2− (pKa 3.4) to nitrous acid (HNO2) yields NO2 from N2O3 and N2O4 homolysis.
“The protonation of NO 2 Ϫ (pK a 3.4) to nitrous acid (HNO 2 ) also yields ⅐ NO 2 from N 2 O 3 and N 2 O 4 homolysis (48).”
From Conjugated linoleic acid is a preferential substrate for fatty acid nitration (2012) · cites this paper as [48]
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References 21 · Cited by 23
- Authors
- Napolitano, A., Crescenzi, O., Camera, E., Giudicianni, I., Picardo, M., & d'Ischia, M.
- Affiliations
- University of Naples Federico II (IT)
- San Gallicano Hospital (IT)
- Corresponding author
- Napolitano, Alessandra
- Venue
- Tetrahedron
- Publisher
- Elsevier BV
- Published
- 2002-06
- Volume
- 58
- Issue
- 25
- Pages
- 5061-5067
- ISSN
- 0040-4020 (ISSN-L)
- OpenAlex
- W2045940124
- Cited by
- 23
- References
- 21
- Citations by year
- 2018: 1 · 2013: 4 · 2012: 1
- FWCI
- 1.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Tetrahedron (publishedVersion)
- Scuola Normale Superiore di Pisa (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Structural and Chemical Analysis of Organic and Inorganic Compounds
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Keywords
- ethyl linoleate, nitrite, 15N labeling, skipped dienes, regioisomers, stereochemistry
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