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The effects of various pulping conditions on crystalline structure of cellulose in cotton linters
Open accessAbstract
In this study, we investigated that how the crystalline structure of cellulose in cotton linters changed during soda, sulfate and organosolve pulping processes by using X-ray diffraction and FT-IR spectroscopy. It was defined that crystalline structure of cellulose in cotton linters was more effected in organosolve pulping than in soda and sulfate pulping. It was found that the degree of crystallinity and crystallite size were higher in organosolve pulping than in soda and sulfate pulping. While cellulose Iα (triclinic) was determined in all organosolve pulp samples, this unit cell structure was defined in only sulfate pulp samples obtained at 130 °C among other pulp samples. It was concluded that not only chemical agents, but also temperature and pressure in cooking digester had major effects on crystalline structure of cellulose in cotton linters during cooking.
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Cited by
Park, S., Baker, J. O., Himmel, M. E., Parilla, P. A., & Johnson, D. K. (2010) · Biotechnology for Biofuels · doi:10.1186/1754-6834-3-10 · Cited by 3,395
Comparison and assessment of methods for cellulose crystallinity determination
Salem, K. S., Kasera, N. K., Rahman, M. A., Jameel, H., Habibi, Y., Eichhorn, S. J., French, A. D., Pal, L., & Lucia, L. A. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00569g · Cited by 600
Additive manufacturing of natural fiber reinforced polymer composites: Processing and prospects
Balla, V. K., Kate, K. H., Satyavolu, J., Singh, P., & Tadimeti, J. G. D. (2019) · Composites Part B: Engineering · doi:10.1016/j.compositesb.2019.106956 · Cited by 580
Crystal transition from cellulose I to cellulose II in NaOH treated Agave americana L. fibre
Oudiani, A. E., Chaabouni, Y., Msahli, S., & Sakli, F. (2011) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2011.06.037 · Cited by 317
Poletto, M., Pistor, V., Zeni, M., & Zattera, A. J. (2011) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2010.12.007 · Cited by 277
Metadata
- Authors
- Gümüskaya, E., Usta, M., & Kirci, H.
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 2003-01
- Volume
- 81
- Issue
- 3
- Pages
- 559-564
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W1999016170
- Cited by
- 227
- References
- 0
- FWCI
- 1.35
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Gümüskaya, E., Usta, M., & Kirci, H. (2003). The effects of various pulping conditions on crystalline structure of cellulose in cotton linters. Polymer Degradation and Stability. https://doi.org/10.1016/s0141-3910(03)00157-5
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