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Ion conductive characteristics of ionic liquids prepared by neutralization of alkylimidazoles
Open accessAbstract
A wide variety of ionic liquids was prepared by the neutralization of five kinds of imidazole derivatives and nine kinds of acids. Their physical and chemical properties such as melting points, glass transition temperature, viscosity, and ionic conductivity were studied. Among these, imidazoles neutralized with imide-type acids were revealed to have lower melting points and lower glass transition temperature than others. These characteristics are quite effective to provide higher ionic conductivity. Especially, N-methylimidazole neutralized with bis(trifluoromethanesulfonyl)imide acid showed 7.23×10−3 S cm−1 at 25 °C. This neutralization method is quite convenient and effective to provide excellent ionic liquid as well as to design suitable models for quaternized onium-type salts.
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Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids
Wilkes, J. S., & Zaworotko, M. J. (1992) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39920000965 · Cited by 1,883
Preparation and polymerization of new organic molten salts; N-alkylimidazolium salt derivatives
Hirao, M., Ito, K., & Ohno, H. (2000) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00334-5 · Cited by 179
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Cited by
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Hallett, J. P., & Welton, T. (2011) · Chemical Reviews · doi:10.1021/cr1003248 · Cited by 12,578
Ionic liquids: solvent properties and organic reactivity
Chiappe, C., & Pieraccini, D. (2005) · Journal of Physical Organic Chemistry · doi:10.1002/poc.863 · Cited by 1,169
Energy storage in electrochemical capacitors: designing functional materials to improve performance
Hall, P. J., Mirzaeian, M., Fletcher, S. I., Sillars, F. B., Rennie, A. J. R., Shitta-Bey, G. O., Wilson, G., Cruden, A., & Carter, R. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00004c · Cited by 1,162
Multiscale Studies on Ionic Liquids
Dong, K., Liu, X., Dong, H., Zhang, X., & Zhang, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00776 · Cited by 773
Ohno, H., & Fukumoto, K. (2007) · Accounts of Chemical Research · doi:10.1021/ar700053z · Cited by 631
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Metadata
- Authors
- Ohno, H., & Yoshizawa, M.
- Venue
- Solid State Ionics
- Publisher
- Elsevier BV
- Published
- 2002-12
- Volume
- 154-155
- Pages
- 303-309
- ISSN
- 0167-2738 (ISSN-L)
- OpenAlex
- W2158543229
- Cited by
- 232
- References
- 2
- FWCI
- 3.61
- Type
- journal article
- Language
- en
- Open access
- green
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- Ohno, H., & Yoshizawa, M. (2002). Ion conductive characteristics of ionic liquids prepared by neutralization of alkylimidazoles. Solid State Ionics. https://doi.org/10.1016/s0167-2738(02)00526-x
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