Cited by 95Heavy metals in environmentAdsorption and biosorption for pollutant removalPhosphorus and nutrient management

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Mutual effects of cadmium and phosphate on their adsorption and desorption by goethite

Wang, Kaijun, Xing, Baoshan·2004·Environmental Pollution

DOI 10.1016/s0269-7491(03)00262-8

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Abstract

Adsorption of cadmium (Cd) and phosphate by oxides or soils has been extensively studied, but the adsorption/desorption kinetics and mutual effects of these two species in co-existing systems has received little attention. In this study, a batch equilibration method was used to investigate the effect of phosphate and its application time on Cd adsorption and desorption on goethite. The influence of Cd and its application time on phosphate sorption and desorption kinetics was also determined. For Cd adsorption, phosphate was introduced into the system by two sequences: pre-treating goethite at 40 (degrees)C for 1 week, and applying with Cd simultaneously. Similarly, for phosphate sorption, Cd was applied by pre-treating goethite at 40 (degrees)C for 1 week or simultaneous addition with phosphate. Results demonstrated that phosphate added to goethite enhanced Cd adsorption, and facilitated Cd release as compared to untreated goethite. Cadmium had slightly higher adsorption, but a significantly faster desorption rate from the goethite simultaneously treated with phosphate and Cd, as compared to phosphate-pretreated goethite. Cadmium and its application time had little impact on phosphate sorption by goethite. However, phosphate desorption kinetics was affected by Cd application time. When the sorption time was short (15 min), phosphate desorption was faster from the goethite that was simultaneously treated with phosphate and Cd, as compared to Cd pretreated or untreated goethite. In contrast, a longer sorption time (4 weeks) resulted in a higher desorption rate of phosphate from Cd pretreated goethite than simultaneously phosphate-Cd treated goethite. This study provided useful information on adsorption/desorption kinetics in complicated Cd-phosphate-goethite systems.

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Authors: Wang, K., & Xing, B.
Affiliations: University of Massachusetts Amherst (US)
Corresponding author: Xing, Baoshan
ORCID: Wang, Kaijun
Xing, Baoshan
Venue: Environmental Pollution
Publisher: Elsevier BV
Published: 2004-01
Volume: 127
Issue: 1
Pages: 13-20
ISSN: 0269-7491 (ISSN-L)
DOI: 10.1016/s0269-7491(03)00262-8
OpenAlex: W2094448107
Cited by: 95
References: 28
Citations by year: 2026: 4 · 2025: 1 · 2024: 8 · 2023: 7 · 2022: 5 · 2021: 1 · 2020: 6 · 2019: 3 · 2018: 4 · 2017: 7 · 2016: 6 · 2015: 3 · 2014: 3 · 2013: 4 · 2012: 2
FWCI: 3.21
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Environmental Pollution (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
Physical Sciences › Environmental Science › Waste Management and Disposal › Phosphorus and nutrient management
Keywords: cadmium, phosphate, goethite, adsorption kinetics, desorption kinetics, metal release, iron oxide minerals, phosphate pretreatment, heavy metal contamination
MeSH terms: Adsorption, Cadmium, Minerals, Phosphates, Soil Pollutants, Hazardous Substances, Iron Compounds

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Mutual effects of cadmium and phosphate on their adsorption and desorption by goethite

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