Cited by 369Terahertz technology and applicationsSpectroscopy and Quantum Chemical StudiesCrystallography and molecular interactions

Noncovalent intermolecular forces in polycrystalline and amorphous saccharides in the far infrared

Walther, Markus, Fischer, Bernd M., Uhd Jepsen, P.·2003·Chemical Physics

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Crossref · 10.1016/s0301-0104(03)00031-4

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  • For both refractive index and absorption coefficient values, spectral features at 48, 55, 60, 74, 85 and 94 cm^-1 characteristic of sucrose at 300 K are well observed in all triplicate spectra for particles with sizes below 150 μm.

    “Additionally, for both refractive index and absorption coefficient values, spectral features at 48, 55, 60, 74, 85 and 94 cm characteristic of sucrose at 300 K [20] are well observed in all triplicate spectra for particles with sizes below 150 m.”
  • Walther et al. reported that the refractive index of a solid spectroscopic pellet obtained from milled sucrose powder diluted with polyethylene is 1.8 on average over the frequency range 0.2-4 THz.

    “Walther et al. [20] reported that the refractive index of a solid spectroscopic pellet obtained from milled sucrose powder diluted with polyethylene is 1.8 on average over the frequency range 0.2-4 THz.”
  • Sucrose has a distinct spectral signature in the terahertz region 0.15-3 THz.

    “Sucrose is a chemical readily available in large quantities and has a distinct spectral signature in the terahertz region 0.15-3 THz [20].”

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References 32 · Cited by 369

Authors
Walther, M., Fischer, B. M., & Uhd Jepsen, P.
Affiliations
University of Freiburg (DE)
Venue
Chemical Physics
Publisher
Elsevier BV
Published
2003-03
Volume
288
Issue
2-3
Pages
261-268
ISSN
0301-0104 (ISSN-L)
OpenAlex
W2154700882
Cited by
369
References
32
Citations by year
2026: 11 · 2025: 9 · 2024: 11 · 2023: 8 · 2022: 13 · 2021: 13 · 2020: 19 · 2019: 14 · 2018: 15 · 2017: 8 · 2016: 18 · 2015: 15 · 2014: 21 · 2013: 20 · 2012: 19
FWCI
18.74
Type
journal article
Language
en
Open access
closed
Locations
  • Chemical Physics (publishedVersion)
  • Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
  • FreiDok plus (Universitätsbibliothek Freiburg) (submittedVersion)
Funders
Bundesministerium für Bildung und Forschung
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Terahertz technology and applications
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
Keywords
hydrogen bonding, amorphous sugars, glucose, fructose, sucrose, intermolecular vibrations, terahertz absorption, van der Waals interactions, hydrogen bond strength

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