Manganese(II) partitioning during experimental precipitation of rhodochrosite–calcite solid solutions from aqueous solutions
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A nearly continuous series between CaCO3 and MnCO3 can be prepared in the laboratory.
“and a nearly continuous series between CaCO3 and MnCO3 can be prepared in the laboratory [6, 13].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [13]
During precipitation of complete (Ca1-xMnx)CO3 solid solutions, Mn2+ cations were commonly enriched in the solid phase at a lower precipitation rate.
“whereas the Mn2+ cations were commonly enriched in the solid phase at a lower precipitation rate [13].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [13]
The a0 value of −3.5 at 5 °C is nearly equal to the a0 value of −4 at 20 °C for synthetic Mn-calcite [Ca0.86Mn0.14CO3].
“which is nearly equal to the a0 value of − 4 (20 °C) for synthetic Mn-calcite [Ca0.86Mn0.14CO3] [13].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [13]
During precipitation of complete (Ca1-xMnx)CO3 solid solutions, no Ca2+ and Mn2+ fractionation between the solid and water was detected at a very high precipitation rate.
“During the precipitation of the complete (Ca1-xMnx)CO3 solid solutions, no Ca2+ and Mn2+ fractionation between the solid and water was detected at a very high precipitation rate”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [13]
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References 49 · Cited by 79
- Authors
- Böttcher, M. E.
- Affiliations
- Carl von Ossietzky Universität Oldenburg (DE)
- Corresponding author
- Böttcher, Michael E.
- ORCID
- Böttcher, Michael E.
- Venue
- Marine Chemistry
- Publisher
- Elsevier BV
- Published
- 1998-11
- Volume
- 62
- Issue
- 3-4
- Pages
- 287-297
- ISSN
- 0304-4203 (ISSN-L)
- OpenAlex
- W2040432132
- Cited by
- 79
- References
- 49
- Citations by year
- 2026: 5 · 2025: 4 · 2024: 3 · 2023: 5 · 2022: 6 · 2021: 5 · 2020: 2 · 2019: 4 · 2018: 7 · 2017: 4 · 2015: 2 · 2014: 2 · 2012: 3
- FWCI
- 4.91
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Marine Chemistry (publishedVersion)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Funders
- Deutsche Forschungsgemeinschaft
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Keywords
- carbonate precipitation, partition coefficient, precipitation kinetics, kutnahorite, activity coefficients
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