Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes
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A similar conductivity/methanol crossover correlation has been observed with new polymeric materials, where protonic conductivity decreases as the methanol barrier property of the film improves.
“A similar conductivity/methanol crossover correlation has been observed with these polymers, where the protonic conductivity decreases as the methanol barrier property of the film improves.”
From Sulfonated Polyphosphazene-Polybenzimidazole Membranes for DMFCs (2005) · cites this paper as [9]
Membranes from UV-cross-linked blends of sulfonated poly[bis(3-methylphenoxy)phosphazene] and polyacrylonitrile used in a DMFC had reduced methanol crossover but lower current-voltage performance than Nafion 117.
“Although the methanol crossover was reduced, the current-voltage performance was lower than that obtained with Nafion 117.”
From Sulfonated Polyphosphazene-Polybenzimidazole Membranes for DMFCs (2005) · cites this paper as [9]
Sulfonated poly(alkylphenoxy)phosphazenes possess acceptably high proton conductivity, crosslinkability, and low methanol permeability.
“who showed that sulfonated poly͑alkylphe-noxy͒phosphazenes possess an acceptably high proton conductivity, crosslinkability, and low methanol permeability.”
From Sulfonated Polyphosphazene-Polybenzimidazole Membranes for DMFCs (2005) · cites this paper as [9]
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References 20 · Cited by 355
- Authors
- Guo, Q., N. Pintauro, P., Tang, H., & O'Connor, S.
- Venue
- Journal of Membrane Science
- Publisher
- Elsevier BV
- Published
- 1999-03
- Volume
- 154
- Issue
- 2
- Pages
- 175-181
- ISSN
- 0376-7388 (ISSN-L)
- OpenAlex
- W2016957512
- Cited by
- 355
- References
- 20
- Citations by year
- 2026: 3 · 2025: 1 · 2024: 4 · 2023: 3 · 2022: 7 · 2021: 4 · 2020: 8 · 2019: 7 · 2018: 11 · 2017: 11 · 2016: 7 · 2015: 14 · 2014: 9 · 2013: 14 · 2012: 21
- FWCI
- 12.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Membrane Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
- Physical Sciences › Engineering › Biomedical Engineering › Membrane-based Ion Separation Techniques
- Keywords
- proton exchange membranes, polyphosphazenes, polymer crosslinking, benzophenone photoinitiator, UV crosslinking, ion exchange capacity, proton conductivity, methanol fuel cells, direct methanol fuel cells, H2/O2 fuel cells, membrane swelling, thermal stability, chemical stability, Nafion 117 comparison
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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