Cited by 355Fuel Cells and Related MaterialsMembrane Separation and Gas TransportMembrane-based Ion Separation Techniques

Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes

Guo, Qunhui, N. Pintauro, Peter, Tang, Hao, O'Connor, Sally·1999·Journal of Membrane Science

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Crossref · 10.1016/s0376-7388(98)00282-8

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  • A similar conductivity/methanol crossover correlation has been observed with new polymeric materials, where protonic conductivity decreases as the methanol barrier property of the film improves.

    “A similar conductivity/methanol crossover correlation has been observed with these polymers, where the protonic conductivity decreases as the methanol barrier property of the film improves.”
  • Membranes from UV-cross-linked blends of sulfonated poly[bis(3-methylphenoxy)phosphazene] and polyacrylonitrile used in a DMFC had reduced methanol crossover but lower current-voltage performance than Nafion 117.

    “Although the methanol crossover was reduced, the current-voltage performance was lower than that obtained with Nafion 117.”
  • Sulfonated poly(alkylphenoxy)phosphazenes possess acceptably high proton conductivity, crosslinkability, and low methanol permeability.

    “who showed that sulfonated poly͑alkylphe-noxy͒phosphazenes possess an acceptably high proton conductivity, crosslinkability, and low methanol permeability.”

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References 20 · Cited by 355

Authors
Guo, Q., N. Pintauro, P., Tang, H., & O'Connor, S.
Venue
Journal of Membrane Science
Publisher
Elsevier BV
Published
1999-03
Volume
154
Issue
2
Pages
175-181
ISSN
0376-7388 (ISSN-L)
OpenAlex
W2016957512
Cited by
355
References
20
Citations by year
2026: 3 · 2025: 1 · 2024: 4 · 2023: 3 · 2022: 7 · 2021: 4 · 2020: 8 · 2019: 7 · 2018: 11 · 2017: 11 · 2016: 7 · 2015: 14 · 2014: 9 · 2013: 14 · 2012: 21
FWCI
12.43
Type
journal article
Language
en
Open access
closed
Locations
Journal of Membrane Science (publishedVersion)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
  • Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
  • Physical Sciences › Engineering › Biomedical Engineering › Membrane-based Ion Separation Techniques
Keywords
proton exchange membranes, polyphosphazenes, polymer crosslinking, benzophenone photoinitiator, UV crosslinking, ion exchange capacity, proton conductivity, methanol fuel cells, direct methanol fuel cells, H2/O2 fuel cells, membrane swelling, thermal stability, chemical stability, Nafion 117 comparison

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