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Photovoltaics from soluble small molecules
Open accessAbstract
Solution-processable small molecules have attractive features for application in photovoltaic cells. They offer the facile processing associated with polymers, yet are easier to synthesize and purify, are monodisperse, and typically show higher charge carrier mobilities. Recent progress in solution-processable small molecule blends has yielded photovoltaic cells with efficiencies exceeding 1%. This article reviews progress in this nascent field and discusses the requirements imposed by the need for charge separation within an interpenetrating network, energy level tuning for light absorption and voltage output, and processing techniques to achieve phase separation on excitonic length scales. Design criteria for next-generation materials are provided.
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Cites
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
Cited by
Small molecule semiconductors for high-efficiency organic photovoltaics
Lin, Y., Li, Y., & Zhan, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15313k · Cited by 1,751
Dang, M. T., Hirsch, L., Wantz, G., & Wuest, J. D. (2013) · Chemical Reviews · doi:10.1021/cr300005u · Cited by 587
Design of Diketopyrrolopyrrole (DPP)‐Based Small Molecules for Organic‐Solar‐Cell Applications
Tang, A., Zhan, C., Yao, J., & Zhou, E. (2017) · Advanced Materials · doi:10.1002/adma.201600013 · Cited by 348
New soluble porphyrin bearing a pyridinylethynyl group as donor for bulk heterojunction solar cells
Sharma, G. D., Daphnomili, D., Biswas, S., & Coutsolelos, A. G. (2013) · Organic Electronics · doi:10.1016/j.orgel.2013.03.023 · Cited by 30
Metadata
- Authors
- Lloyd, M. T., Anthony, J. E., & Malliaras, G. G.
- Venue
- Materials Today
- Publisher
- Elsevier BV
- Published
- 2007-11
- Volume
- 10
- Issue
- 11
- Pages
- 34-41
- ISSN
- 1369-7021 (ISSN-L)
- OpenAlex
- W2081761083
- Cited by
- 312
- References
- 1
- FWCI
- 28.66
- Type
- journal article
- Language
- en
- Open access
- hybrid
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