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4. On the Equilibrium of Vapour at a Curved Surface of Liquid
Abstract
In a closed vessel containing only a liquid and its vapour, all at one temperature, the liquid rests, with its free surface raised or depressed in capillary tubes and in the neighbourhood of the solid boundary, in permanent equilibrium according to the same law of relation between curvature and pressure as in vessels open to the air. The permanence of this equilibrium implies physical equilibrium between the liquid and the vapour in contact with it at all parts of its surface. But the pressure of the vapour at different levels differs according to hydrostatic law. Hence the pressure of saturated vapour in contact with a liquid differs according to the curvature of the bounding surface, being less when the liquid is concave, and greater when it is convex.
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Citations
Cited by
Riess, J. G. (2001) · Chemical Reviews · doi:10.1021/cr970143c · Cited by 773
Thermodynamic functions of water and ice confined to 2nm radius pores
Tombari, E., Salvetti, G., Ferrari, C., & Johari, G. P. (2005) · The Journal of Chemical Physics · doi:10.1063/1.1862244 · Cited by 90
Metadata
- Authors
- Thomson, W.
- Venue
- Proceedings of the Royal Society of Edinburgh
- Publisher
- Cambridge University Press (CUP)
- Published
- 1872
- Volume
- 7
- Pages
- 63-68
- ISSN
- 0370-1646 (ISSN-L)
- OpenAlex
- W2470867721
- Cited by
- 350
- References
- 0
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Thomson, W. (1872). 4. On the Equilibrium of Vapour at a Curved Surface of Liquid. Proceedings of the Royal Society of Edinburgh. https://doi.org/10.1017/s0370164600041729
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.