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Cited by 470

The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.

Hollow Fiber-Protected Liquid-Phase Microextraction of Triazine Herbicides

Shen, Gang, Lee, Hian Kee·2002·Analytical Chemistry

Abstract

A new microextraction technique termed hollow fiber-protected liquid-phase microextraction (LPME) was developed. Triazines were employed as model compounds to assess the extraction procedure and were determined by gas chromatography/mass spectrometry. Toluene functioned as both the extraction solvent and the impregnation solvent. Some important extraction parameters, such as effect of salt, agitation, pH, and exposure time were optimized. The new method provided good average enrichment factors of > 150 for eight analytes, good repeatability (RSDs <3.50%, n = 7), and good linearity (r2 > or = 0.9995) for spiked deionized water samples. The limits of detection (LODs) were in the range of 0.007-0.063 microg/L (S/N = 3) under selected ion monitoring mode. In addition to enrichment, hollow fiber-protected LPME also served as a technique for sample cleanup because of the selectivity of the membrane, which prevented large molecules and extraneous materials, such as humic acids in solution, from being extracted. The utilization of this procedure in the extraction of a slurry sample (mixture of soil and water) also gave good precision (RSDs <5.00%, n = 3) and LODs (0.04-0.18 microg/L, S/N = 3). Finally, the comparison of the new method with the static solvent drop LPME and solid-phase microextraction was performed. The results demonstrated that hollow fiber-protected LPME was a fast, accurate, and stable sample pretreatment method that gave very good enrichment factors for the extraction of triazine herbicides from aqueous or slurry samples.

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Metadata

Authors
Shen, G., & Lee, H. K.
Venue
Analytical Chemistry
Published
2001-12-19
Volume
74
Issue
3
Pages
648-654
ISSN
  • 0003-2700 (ISSN-L)
  • 1520-6882
OpenAlex
W2088487256
Cited by
470
References
13
FWCI
10.18
Type
journal article
Language
en
Open access
closed

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