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Measurement of Gas-Phase Hydroperoxides by Chemical Ionization Mass Spectrometry

Crounse, John D., McKinney, Karena A., Kwan, Alan J., Wennberg, Paul O.·2006·Analytical Chemistry

Abstract

A new method for the detection of gas-phase hydroperoxides is described. The clustering chemistry of CF3O- is exploited to produce speciated measurements of several hydroperoxides with high sensitivity and fast time response. Correspondence of airborne observations made with this technique and the established HPLC method is illustrated. CF3O- appears to be a highly versatile reagent ion for measurements of both weak and strong acids in the atmosphere.

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Metadata

Authors
Crounse, J. D., McKinney, K. A., Kwan, A. J., & Wennberg, P. O.
Venue
Analytical Chemistry
Published
2006-09-01
Volume
78
Issue
19
Pages
6726-6732
ISSN
  • 0003-2700 (ISSN-L)
  • 1520-6882
OpenAlex
W2039720350
Cited by
335
References
0
FWCI
4.29
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.