The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Ion-Selective Electrodes with Three-Dimensionally Ordered Macroporous Carbon as the Solid Contact
Abstract
Electrodes with three-dimensionally ordered macroporous (3DOM) carbon as the intermediate layer between an ionophore-doped solvent polymeric membrane and a metal contact are presented as a novel approach to solid-contact ion-selective electrodes (SC-ISEs). Due to the well-interconnected pore and wall structure of 3DOM carbon, filling of the 3DOM pores with an electrolyte solution results in a nanostructured material that exhibits high ionic and electric conductivity. The long-term drift of freshly prepared SC-ISEs with 3DOM carbon contacts is only 11.7 microV/h, and does not increase when in contact with solution for 1 month, making this the most stable SC-ISE reported so far. The electrodes show good resistance to the interference from oxygen. Moreover, in contrast to previously reported SC-ISEs with conducting polymers as the intermediate layer, 3DOM carbon is an electron conductor rather than a semiconductor, eliminating any light interference.
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Cites
Bobacka, J. (1999) · Analytical Chemistry · doi:10.1021/ac990497z · Cited by 686
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Mesoporous materials and electrochemistry
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Electrochemical sensing based on carbon nanotubes
Yáñez-Sedeño, P., Pingarrón, J. M., Riu, J., & Rius, F. X. (2010) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2010.06.006 · Cited by 294
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Metadata
- Authors
- Lai, C.-Z., Fierke, M. A., Stein, A., & Bühlmann, P.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-18
- Volume
- 79
- Issue
- 12
- Pages
- 4621-4626
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W2055692889
- Cited by
- 286
- References
- 1
- FWCI
- 7.80
- Type
- journal article
- Language
- en
- Open access
- closed
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