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Electropolymerized Molecularly Imprinted Polymers as Receptor Layers in Capacitive Chemical Sensors
Open accessAbstract
The first application of molecularly imprinted polymers to chemical sensors with capacitive detection is described. The sensitive layer was prepared by electropolymerization of phenol on gold electrodes in the presence of the template (phenylalanine). The insulating properties of the polymer layer were studied by electrochemical impedance spectroscopy. Electrical leakages through the polymer layer were suppressed by deposition of a self-assembled monolayer of mercaptophenol before polymerization and of alkanethiol after polymerization. At the final stage of sensor preparation, the template was removed. The multilayer system obtained displayed a decrease in electrical capacitance on addition of phenylalanine. Only a low response was observed toward other amino acids and phenol.
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Cited by
Stimulus-responsive hydrogels: theory, modern advances, and applications
Koetting, M. C., Peters, J. T., Steichen, S. D., & Peppas, N. A. (2015) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2015.04.001 · Cited by 1,191
Riskin, M., Tel-Vered, R., Bourenko, T., Granot, E., & Willner, I. (2008) · Journal of the American Chemical Society · doi:10.1021/ja711278c · Cited by 295
Metadata
- Authors
- Panasyuk, T. L., Mirsky, V. M., Piletsky, S. A., & Wolfbeis, O. S.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-09-11
- Volume
- 71
- Issue
- 20
- Pages
- 4609-4613
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W2007712302
- Cited by
- 273
- References
- 0
- FWCI
- 7.94
- Type
- journal article
- Language
- en
- Open access
- green
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- Panasyuk, T. L., Mirsky, V. M., Piletsky, S. A., & Wolfbeis, O. S. (1999). Electropolymerized Molecularly Imprinted Polymers as Receptor Layers in Capacitive Chemical Sensors. Analytical Chemistry. https://doi.org/10.1021/ac9903196
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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