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Two New Luminescent Cd(II)-Metal–Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42–, and Cr2O72– in Aqueous Solution
Abstract
Two new luminescent Cd(II)-metal–organic frameworks (MOFs), {[Cd(L)(BPDC)]·2H 2 O} n ( 1 ) and {[Cd(L)(SDBA)(H 2 O)]·0.5H 2 O} n ( 2 ) [L = 4,4′-(2,5-bis(methylthio)-1,4-phenylene)dipyridine, H 2 BPDC = 4,4′-biphenyldicarboxylic acid, H 2 SDBA = 4,4′-sulfonyldibenzoic acid], have been solvothermally synthesized using Cd 2+ ion and L ligand in the presence of auxiliary ligands and characterized by infrared spectroscopy, elemental analysis, powder X-ray diffraction, and thermogravimetry measurement. Topological analyses reveal that MOF 1 is a 6-connected 3-fold interpenetrating pcu network, and MOF 2 is a new 4-connected 2-fold interpenetrating network. Fluorescence titration, cyclic and anti-interference experiments demonstrate that MOFs 1 and 2 both are excellent probes for Fe 3+, CrO 4 2–, and Cr 2 O 7 2– . The mechanisms of quenching are also deeply studied.
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Andrews, N. C. (1999) · New England Journal of Medicine · doi:10.1056/nejm199912233412607 · Cited by 2,130
Cited by
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Wang, B., Yang, Q., Guo, C., Sun, Y., Xie, L.-H., & Li, J.-R. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b00918 · Cited by 423
Metadata
- Authors
- Chen, S., Shi, Z., Qin, L., Jia, H., & Zheng, H.
- Venue
- Crystal Growth & Design
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-08
- Volume
- 17
- Issue
- 1
- Pages
- 67-72
- ISSN
- 1528-7483 (ISSN-L)
- 1528-7505
- OpenAlex
- W2559386428
- Cited by
- 324
- References
- 1
- FWCI
- 17.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Two New Luminescent Cd(II)-Metal–Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42–, and Cr2O72– in Aqueous Solution. https://app.cochat.ai/papers/10.1021/acs.cgd.6b01197
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- Chen, S., Shi, Z., Qin, L., Jia, H., & Zheng, H. (2017). Two New Luminescent Cd(II)-Metal–Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42–, and Cr2O72– in Aqueous Solution. Crystal Growth & Design. https://doi.org/10.1021/acs.cgd.6b01197
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