Improving the Stability and Gas Adsorption Performance of Acylamide Group Functionalized Zinc Metal–Organic Frameworks through Coordination Group Optimization

Jia, Yan-Yuan; Liu, Xiao-Ting; Feng, Rui; Zhang, Shi-Yu; Zhang, Ping; He, Ya-Bing; Zhang, Ying-Hui; Bu, Xian-He

doi:10.1021/acs.cgd.7b00119

Improving the Stability and Gas Adsorption Performance of Acylamide Group Functionalized Zinc Metal–Organic Frameworks through Coordination Group Optimization

In order to elucidate the effect of the structure on stability and gas adsorption performance, three porous Zn(II) metal–organic frameworks, NKU -106, NKU -107, and NKU -108, have been constructed. NKU- 106 and NKU- 107 assembled from acylamide functionalized tetracarboxylate ligand exhibit low s…