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Cited by 339

The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.

N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production

Zhou, Weijia, Zhou, Jian, Zhou, Yucheng, Lu, Jia, Zhou, Kai, Yang, Linjing, Tang, Zhenghua, Li, Ligui, Chen, Shaowei·2015·Chemistry of Materials

Abstract

Development of non-noble-metal catalysts for hydrogen evolution reaction (HER) with both excellent activity and robust stability has remained a key challenge in the past decades. Herein, for the first time, N-doped carbon-wrapped cobalt nanoparticles supported on N-doped graphene nanosheets were prepared by a facile solvothermal procedure and subsequent calcination at controlled temperatures. The electrocatalytic activity for HER was examined in 0.5 M H 2 SO 4 . Electrochemical measurements showed a small overpotential of only −49 mV with a Tafel slope of 79.3 mV/dec. Theoretical calculations based on density functional theory showed that the catalytically active sites were due to carbon atoms promoted by the entrapped cobalt nanoparticles. The results may offer a new methodology for the preparation of effective catalysts for water splitting technology.

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Metadata

Authors
Zhou, W., Zhou, J., Zhou, Y., Lu, J., Zhou, K., Yang, L., Tang, Z., Li, L., & Chen, S.
Venue
Chemistry of Materials
Published
2015-03-12
Volume
27
Issue
6
Pages
2026-2032
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2145156033
Cited by
339
References
36
FWCI
16.52
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production. https://app.cochat.ai/papers/10.1021/acs.chemmater.5b00331
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Zhou, W., Zhou, J., Zhou, Y., Lu, J., Zhou, K., Yang, L., Tang, Z., Li, L., & Chen, S. (2015). N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b00331

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