The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production
Abstract
Development of non-noble-metal catalysts for hydrogen evolution reaction (HER) with both excellent activity and robust stability has remained a key challenge in the past decades. Herein, for the first time, N-doped carbon-wrapped cobalt nanoparticles supported on N-doped graphene nanosheets were prepared by a facile solvothermal procedure and subsequent calcination at controlled temperatures. The electrocatalytic activity for HER was examined in 0.5 M H 2 SO 4 . Electrochemical measurements showed a small overpotential of only −49 mV with a Tafel slope of 79.3 mV/dec. Theoretical calculations based on density functional theory showed that the catalytically active sites were due to carbon atoms promoted by the entrapped cobalt nanoparticles. The results may offer a new methodology for the preparation of effective catalysts for water splitting technology.
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Metadata
- Authors
- Zhou, W., Zhou, J., Zhou, Y., Lu, J., Zhou, K., Yang, L., Tang, Z., Li, L., & Chen, S.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-12
- Volume
- 27
- Issue
- 6
- Pages
- 2026-2032
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2145156033
- Cited by
- 339
- References
- 36
- FWCI
- 16.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, W., Zhou, J., Zhou, Y., Lu, J., Zhou, K., Yang, L., Tang, Z., Li, L., & Chen, S. (2015). N-Doped Carbon-Wrapped Cobalt Nanoparticles on N-Doped Graphene Nanosheets for High-Efficiency Hydrogen Production. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b00331
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