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Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis
Open accessAbstract
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when synthesized in the presence of monocarboxylic acid modulators under the most commonly employed conditions. We unequivocally demonstrate that missing cluster defects are the predominant defect and that their concentration (and thus the porosity and composition of the material) can be tuned to a remarkable extent by altering the concentration and/or acidity of the modulator. Finally, we attempt to rationalize these observations by speculating on the underlying solution chemistry.
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Cited by
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Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
Ma, X., Liu, H., Yang, W., Mao, G., Zheng, L., & Jiang, H.-L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05032 · Cited by 445
The application of different typological and structural MOFs-based materials for the dyes adsorption
Jiang, D., Chen, M., Wang, H., Zeng, G., Huang, D., Cheng, M., Liu, Y., Xue, W., & Wang, Z. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.11.002 · Cited by 435
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Metadata
- Authors
- Shearer, G. C., Chavan, S., Bordiga, S., Svelle, S., Olsbye, U., & Lillerud, K. P.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-05-31
- Volume
- 28
- Issue
- 11
- Pages
- 3749-3761
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2419604106
- Cited by
- 1,437
- References
- 0
- FWCI
- 35.30
- Type
- journal article
- Language
- en
- Open access
- green
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- The paper
- Shearer, G. C., Chavan, S., Bordiga, S., Svelle, S., Olsbye, U., & Lillerud, K. P. (2016). Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.6b00602
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