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Controlled Synthesis of Hollow Co–Mo Mixed Oxide Nanostructures and Their Electrocatalytic and Lithium Storage Properties
Abstract
Hollow mixed metal oxides have received much attention owing to their great performance for wide potential applications. Here, we have successfully prepared hollow Co–Mo mixed oxide nanostructures with controlled structure and compositions, including hollow Co 3 O 4 /CoMoO 4 heterostructures and ball-in-ball CoMoO 4 nanospheres. Uniform CoMo-hybrid precursors are prepared through one-pot solvothermal method and then transformed into hollow structures after thermal treatment. Importantly, this strategy can be used to prepare other ternary Mo-based oxides. In view of the unique heterostructure with hollow structure, the Co 3 O 4 /CoMoO 4 heterostructures exhibit much better electrocatalytic activity for the oxygen evolution reaction than CoMoO 4 . Moreover, the as-synthesized carbon-coated Co 3 O 4 /CoMoO 4 nanospheres show excellent lithium storage properties. Our result described here provides a method to fabricate other mixed metal oxides with complicated structure.
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“In this content, Prussian blue analogues (PBAs) with uniform sizes, various compositions, diverse morphologies, and architectures can serve as ideal precursors to prepare hollow and porous nanostructures.40−42”
From Prussian Blue Analogues Derived Penroseite (Ni,Co)Se 2 Nanocages Anchored on 3D Graphene Aerogel for Efficient Water Splitting (2017) · cites this paper as [42]
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Metadata
- Authors
- Yang, Y., Wang, S., Jiang, C., Lu, Q., Tang, Z., & Wang, X.
- Affiliations
- State Key Laboratory of New Ceramics and Fine Processing (CN)
- Corresponding author
- Wang, Xun
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-29
- Volume
- 28
- Issue
- 7
- Pages
- 2417-2423
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2304991334
- Cited by
- 113
- References
- 51
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 5 · 2023: 8 · 2022: 7 · 2021: 11 · 2020: 13 · 2019: 18 · 2018: 15 · 2017: 23 · 2016: 7
- FWCI
- 5.70
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry of Materials (publishedVersion)
- Funders
- National Natural Science Foundation of China (21431003, 21521091)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Keywords
- hollow nanostructures, cobalt molybdate, ternary metal oxides, oxygen evolution reaction, electrocatalysis, lithium storage, carbon coating, solvothermal synthesis, heat treatment
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