The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Adsorption of a Catalytically Accessible Polyoxometalate in a Mesoporous Channel-type Metal–Organic Framework
Open accessAbstract
A Keggin-type polyoxometalate (H 3 PW 12 O 40 ) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW 12 @NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Finally, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW 12 @NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.
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Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Cited by
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks
Samaniyan, M., Mirzaei, M., Khajavian, R., Eshtiagh-Hosseini, H., & Streb, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03439 · Cited by 389
Kim, M., Kim, S., Park, J., Lee, S., Jang, I., Kim, S., Lee, C. Y., Kwon, O. J., Ham, H. C., Hupp, J. T., et al. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202300673 · Cited by 34
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Metadata
- Authors
- Buru, C. T., Li, P., Mehdi, B. L., Dohnalkova, A., Platero-Prats, A. E., Browning, N. D., Chapman, K. W., Hupp, J. T., & Farha, O. K.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-07
- Volume
- 29
- Issue
- 12
- Pages
- 5174-5181
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2618193709
- Cited by
- 175
- References
- 1
- FWCI
- 8.36
- Type
- journal article
- Language
- en
- Open access
- green
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- Buru, C. T., Li, P., Mehdi, B. L., Dohnalkova, A., Platero-Prats, A. E., Browning, N. D., Chapman, K. W., Hupp, J. T., & Farha, O. K. (2017). Adsorption of a Catalytically Accessible Polyoxometalate in a Mesoporous Channel-type Metal–Organic Framework. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.7b00750
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