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Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications
Abstract
Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.
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Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Nam, K. W., Park, S. S., dos Reis, R., Dravid, V. P., Kim, H., Mirkin, C. A., & Stoddart, J. F. (2019) · Nature Communications · doi:10.1038/s41467-019-12857-4 · Cited by 688
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Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Dislocated Bilayer MOF Enables High‐Selectivity Photocatalytic Reduction of CO2 to CO
Liang, J., Yu, H., Shi, J., Li, B., Wu, L., & Wang, M. (2023) · Advanced Materials · doi:10.1002/adma.202209814 · Cited by 270
Ramakrishnan, S., Velusamy, D. B., Sengodan, S., Nagaraju, G., Kim, D. H., Kim, A. R., & Yoo, D. J. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120752 · Cited by 205
Metadata
- Authors
- Chakraborty, G., Park, I.-H., Medishetty, R., & Vittal, J. J.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-02-25
- Volume
- 121
- Issue
- 7
- Pages
- 3751-3891
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W3132590780
- Cited by
- 928
- References
- 2
- FWCI
- 5.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chakraborty, G., Park, I.-H., Medishetty, R., & Vittal, J. J. (2021). Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.0c01049
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