The DOI matches its Crossref record; 137 of the 137 references it cites were found in a registry or an index.
Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis
Open accessAbstract
For more than 70 years, nitrogen-centered radicals have been recognized as potent synthetic intermediates. This review is a survey designed for use by chemists engaged in target-oriented synthesis. This review summarizes the recent paradigm shift in access to and application of N -centered radicals enabled by visible-light photocatalysis. This shift broadens and streamlines approaches to many small molecules because visible-light photocatalysis conditions are mild. Explicit attention is paid to innovative advances in N–X bonds as radical precursors, where X = Cl, N, S, O, and H. For clarity, key mechanistic data is noted, where available. Synthetic applications and limitations are summarized to illuminate the tremendous utility of photocatalytically generated nitrogen-centered radicals.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
1 retracted
Eosin Y catalysed photoredox synthesis: a review
Srivastava, V., & Singh, P. P. (2017) · RSC Advances · doi:10.1039/c7ra05444k · Cited by 336
RetractedPrier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Romero, N. A., & Nicewicz, D. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00057 · Cited by 6,283
Photoredox Catalysis in Organic Chemistry
Shaw, M. H., Twilton, J., & MacMillan, D. W. C. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01449 · Cited by 3,186
Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design
Meanwell, N. A. (2018) · Journal of Medicinal Chemistry · doi:10.1021/acs.jmedchem.7b01788 · Cited by 2,655
Introduction of Fluorine and Fluorine‐Containing Functional Groups
Liang, T., Neumann, C. N., & Ritter, T. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201206566 · Cited by 2,564
Modern physical organic chemistry
(2006) · Choice Reviews Online · doi:10.5860/choice.43-3398 · Cited by 2,312
The merger of transition metal and photocatalysis
Twilton, J., Le, C., Zhang, P., Shaw, M. H., Evans, R. W., & MacMillan, D. W. C. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0052 · Cited by 2,226
Kalyanasundaram, K. (1982) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(82)85003-0 · Cited by 1,943
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
Warren, J. J., Tronic, T. A., & Mayer, J. M. (2010) · Chemical Reviews · doi:10.1021/cr100085k · Cited by 1,692
Metadata
- Authors
- Kwon, K., Simons, R. T., Nandakumar, M., & Roizen, J. L.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-10-08
- Volume
- 122
- Issue
- 2
- Pages
- 2353-2428
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W3204170622
- Cited by
- 389
- References
- 137
- FWCI
- 2.13
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis. https://app.cochat.ai/papers/10.1021/acs.chemrev.1c00444
- The paper
- Kwon, K., Simons, R. T., Nandakumar, M., & Roizen, J. L. (2022). Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.1c00444
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
