The DOI matches its Crossref record; 119 of the 119 references it cites were found in a registry or an index.
σ-Hole Bond vs π-Hole Bond: A Comparison Based on Halogen Bond
Abstract
The σ-hole and π-hole are the regions with positive surface electrostatic potential on the molecule entity; the former specifically refers to the positive region of a molecular entity along extension of the Y-Ge/P/Se/X covalent σ-bond (Y = electron-rich group; Ge/P/Se/X = Groups IV-VII), while the latter refers to the positive region in the direction perpendicular to the σ-framework of the molecular entity. The directional noncovalent interactions between the σ-hole or π-hole and the negative or electron-rich sites are named σ-hole bond or π-hole bond, respectively. The contributions from electrostatic, charge transfer, and other terms or Coulombic interaction to the σ-hole bond and π-hole bond were reviewed first followed by a brief discussion on the interplay between the σ-hole bond and the π-hole bond as well as application of the two types of noncovalent interactions in the field of anion recognition. It is expected that this review could stimulate further development of the σ-hole bond and π-hole bond in theoretical exploration and practical application in the future.
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Cites
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Cited by
Chalcogen bonding in synthesis, catalysis and design of materials
Mahmudov, K. T., Kopylovich, M. N., Guedes da Silva, M. F. C., & Pombeiro, A. J. L. (2017) · Dalton Transactions · doi:10.1039/c7dt01685a · Cited by 466
Metadata
- Authors
- Wang, H., Wang, W., & Jin, W. J.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-17
- Volume
- 116
- Issue
- 9
- Pages
- 5072-5104
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2278348890
- Cited by
- 631
- References
- 119
- FWCI
- 3.30
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
