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Dual Catalysis Strategies in Photochemical Synthesis
Open accessAbstract
The interaction between an electronically excited photocatalyst and an organic molecule can result in the genertion of a diverse array of reactive intermediates that can be manipulated in a variety of ways to result in synthetically useful bond constructions. This Review summarizes dual-catalyst strategies that have been applied to synthetic photochemistry. Mechanistically distinct modes of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer, and energy transfer. We focus upon the cooperative interactions of photocatalysts with redox mediators, Lewis and Brønsted acids, organocatalysts, enzymes, and transition metal complexes.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Asymmetric photochemical reactions in solution
Inoue, Y. (1992) · Chemical Reviews · doi:10.1021/cr00013a001 · Cited by 657
Asymmetric photochemistry in solution
Rau, H. (1983) · Chemical Reviews · doi:10.1021/cr00057a003 · Cited by 336
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Metadata
- Authors
- Skubi, K. L., Blum, T. R., & Yoon, T. P.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-04-25
- Volume
- 116
- Issue
- 17
- Pages
- 10035-10074
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2342772717
- Cited by
- 2,686
- References
- 3
- FWCI
- 7.21
- Type
- journal article
- Language
- en
- Open access
- hybrid
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