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Advances in Conjugated Microporous Polymers
Open accessAbstract
Conjugated microporous polymers (CMPs) are a unique class of materials that combine extended π-conjugation with a permanently microporous skeleton. Since their discovery in 2007, CMPs have become established as an important subclass of porous materials. A wide range of synthetic building blocks and network-forming reactions offers an enormous variety of CMPs with different properties and structures. This has allowed CMPs to be developed for gas adsorption and separations, chemical adsorption and encapsulation, heterogeneous catalysis, photoredox catalysis, light emittance, sensing, energy storage, biological applications, and solar fuels production. Here we review the progress of CMP research since its beginnings and offer an outlook for where these materials might be headed in the future. We also compare the prospect for CMPs against the growing range of conjugated crystalline covalent organic frameworks (COFs).
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer
Xie, Y., Wang, T.-T., Liu, X.-H., Zou, K., & Deng, W.-Q. (2013) · Nature Communications · doi:10.1038/ncomms2960 · Cited by 772
A Particulate Photocatalyst Water-Splitting Panel for Large-Scale Solar Hydrogen Generation
Goto, Y., Hisatomi, T., Wang, Q., Higashi, T., Ishikiriyama, K., Maeda, T., Sakata, Y., Okunaka, S., Tokudome, H., Katayama, M., et al. (2018) · Joule · doi:10.1016/j.joule.2017.12.009 · Cited by 754
Cited by
Porous organic polymers as a platform for sensing applications
Wang, S., Li, H., Huang, H., Cao, X., Chen, X., & Cao, D. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00059h · Cited by 363
Metadata
- Authors
- Lee, J.-S. M., & Cooper, A. I.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-28
- Volume
- 120
- Issue
- 4
- Pages
- 2171-2214
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W3003716272
- Cited by
- 1,394
- References
- 4
- FWCI
- 6.20
- Type
- journal article
- Language
- en
- Open access
- hybrid
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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