The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Insights into the Electron-Transfer Mechanism of Permanganate Activation by Graphite for Enhanced Oxidation of Sulfamethoxazole
Abstract
Abstract Many reagents as electron sacrificers have been recently investigated to induce decomposition of permanganate (KMnO4) to produce highly reactive intermediate Mn species toward oxidation of organic contaminants; however, this strategy meanwhile causes low KMnO4 utilization efficiency. This study surprisingly found that graphite can mediate direct electron transfer from organics (e.g., sulfamethoxazole (SMX)) to KMnO4, resulting in high KMnO4 utilization efficiency, rather than reductive sites of graphite-induced conversion of KMnO4 to highly reactive intermediate Mn species. The galvanic oxidation process (GOP) and comparative experiments of different organic contaminants prove that the KMnO4/graphite system mainly extracts electrons from organic contaminants via a one-electron pathway instead of a two-electron pathway. More importantly, the KMnO4/graphite system has superior reusability, graphite can keep a long-lasting reactivity, and the KMnO4 utilization efficiency elevates significantly after each cycle of graphite. The transformation of SMX in the KMnO4/graphite system mainly includes self-coupling, hydroxylation, oxidation, and hydrolytic reaction. The work will improve insights into the electron-transfer mechanism and unveil the advantages of efficient KMnO4 utilization in the KMnO4-based technologies in environmental remediation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Casida, M. E., Jamorski, C., Casida, K. C., & Salahub, D. R. (1998) · The Journal of Chemical Physics · doi:10.1063/1.475855 · Cited by 5,009
Absolute electronegativity and hardness correlated with molecular orbital theory
Pearson, R. G. (1986) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.83.22.8440 · Cited by 1,771
Yun, E.-T., Lee, J. H., Kim, J., Park, H.-D., & Lee, J. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b00959 · Cited by 1,175
Luo, R., Li, M., Wang, C., Zhang, M., Nasir Khan, M. A., Sun, X., Shen, J., Han, W., Wang, L., & Li, J. (2019) · Water Research · doi:10.1016/j.watres.2018.10.087 · Cited by 1,060
Activation of Peroxydisulfate on Carbon Nanotubes: Electron-Transfer Mechanism
Ren, W., Xiong, L., Yuan, X., Yu, Z., Zhang, H., Duan, X., & Wang, S. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b05475 · Cited by 811
Self-citationRen, W., Xiong, L., Nie, G., Zhang, H., Duan, X., & Wang, S. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.9b06208 · Cited by 766
Self-citationZhou, Z., Liu, X., Sun, K., Lin, C., Ma, J., He, M., & Ouyang, W. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.04.213 · Cited by 677
Rasool, K., Pandey, R. P., Rasheed, P. A., Buczek, S., Gogotsi, Y., & Mahmoud, K. A. (2019) · Materials Today · doi:10.1016/j.mattod.2019.05.017 · Cited by 590
Xu, M., Li, J., Yan, Y., Zhao, X., Yan, J., Zhang, Y., Lai, B., Chen, X., & Song, L. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.03.075 · Cited by 512
Self-citationEvaluation of the sp2/sp3 ratio in amorphous carbon structure by XPS and XAES
Lascovich, J. C., Giorgi, R., & Scaglione, S. (1991) · Applied Surface Science · doi:10.1016/0169-4332(91)90098-5 · Cited by 459
Oxidation of sulfamethoxazole and related antimicrobial agents by TiO2 photocatalysis
Hu, L., Flanders, P. M., Miller, P. L., & Strathmann, T. J. (2007) · Water Research · doi:10.1016/j.watres.2007.02.026 · Cited by 410
Degradation of sulfamethoxazole by persulfate assisted micrometric Fe0 in aqueous solution
Ghauch, A., Ayoub, G., & Naim, S. (2013) · Chemical Engineering Journal · doi:10.1016/j.cej.2013.05.045 · Cited by 328
Sun, B., Guan, X., Fang, J., & Tratnyek, P. G. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b03111 · Cited by 320
Zero-valent iron (ZVI) activation of persulfate (PS) for oxidation of bentazon in water
Wei, X., Gao, N., Li, C., Deng, Y., Zhou, S., & Li, L. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.08.120 · Cited by 284
Pestovsky, O., & Bakac, A. (2006) · Inorganic Chemistry · doi:10.1021/ic051868z · Cited by 262
Chen, J., Qu, R., Pan, X., & Wang, Z. (2016) · Water Research · doi:10.1016/j.watres.2016.07.041 · Cited by 196
Tian, S.-Q., Wang, L., Liu, Y.-L., Yang, T., Huang, Z.-S., Wang, X.-S., He, H.-Y., Jiang, J., & Ma, J. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b00180 · Cited by 190
Liang, C., & Bruell, C. J. (2008) · Industrial & Engineering Chemistry Research · doi:10.1021/ie070820l · Cited by 169
Graphene in 3‐dimensions: Towards graphite origami
Ebbesen, T. W., & Hiura, H. (1995) · Advanced Materials · doi:10.1002/adma.19950070618 · Cited by 166
Transformation of Sulfamethazine by Manganese Oxide in Aqueous Solution
Gao, J., Hedman, C., Liu, C., Guo, T., & Pedersen, J. A. (2012) · Environmental Science & Technology · doi:10.1021/es202492h · Cited by 166
Xu, K., Ben, W., Ling, W., Zhang, Y., Qu, J., & Qiang, Z. (2017) · Water Research · doi:10.1016/j.watres.2017.06.037 · Cited by 151
Jiang, J., Gao, Y., Pang, S., Lu, X., Zhou, Y., Ma, J., & Wang, Q. (2014) · Environmental Science & Technology · doi:10.1021/es504796h · Cited by 150
Reinvestigation of the Role of Humic Acid in the Oxidation of Phenols by Permanganate
Sun, B., Zhang, J., Du, J., Qiao, J., & Guan, X. (2013) · Environmental Science & Technology · doi:10.1021/es404138s · Cited by 133
Guo, K., Zhang, J., Li, A., Xie, R., Liang, Z., Wang, A., Ling, L., Li, X., Li, C., & Fang, J. (2018) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.8b00402 · Cited by 101
Willach, S., Lutze, H. V., Eckey, K., Löppenberg, K., Lüling, M., Terhalle, J., Wolbert, J. B., Jochmann, M. A., Kärst, U., & Schmidt, T. C. (2017) · Water Research · doi:10.1016/j.watres.2017.06.001 · Cited by 89
Chlorination of bisphenol S: Kinetics, products, and effect of humic acid
Gao, Y., Jiang, J., Zhou, Y., Pang, S., Ma, J., Jiang, C., Yang, Y., Huang, Z., Gu, J., Guo, Q., et al. (2017) · Water Research · doi:10.1016/j.watres.2017.12.049 · Cited by 77
Oxidation of non-steroidal anti-inflammatory drugs with aqueous permanganate
Rodríguez-Álvarez, T., Rodil, R., Quintana, J. B., Triñanes, S., & Cela, R. (2013) · Water Research · doi:10.1016/j.watres.2013.03.034 · Cited by 66
Enhanced Transformation of Emerging Contaminants by Permanganate in the Presence of Redox Mediators
Shi, Z., Jin, C., Bai, R., Gao, Z., Zhang, J., Zhu, L., Zhao, Z., & Strathmann, T. J. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b05711 · Cited by 64
Zhao, X., Ma, J., Jiang, J., Bao, Y., & Liu, H. (2016) · Separation and Purification Technology · doi:10.1016/j.seppur.2016.05.060 · Cited by 29
Cited by
Meng, Y., Liu, Y.-Q., Wang, C., Si, Y., Wang, Y.-J., Xia, W.-Q., Liu, T., Cao, X., Guo, Z.-Y., Chen, J.-J., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-49605-2 · Cited by 336
Huang, B., Wu, Z., Wang, X., Song, X., Zhou, H., Zhang, H., Zhou, P., Liu, W., Xiong, Z., & Lai, B. (2023) · Environmental Science & Technology · doi:10.1021/acs.est.3c05509 · Cited by 281
Self-citation
Metadata
- Authors
- Peng, J., Zhou, P., Zhou, H., Liu, W., Zhang, H., Zhou, C., Lai, L., Ao, Z., Su, S., & Lai, B.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-05-28
- Volume
- 55
- Issue
- 13
- Pages
- 9189-9198
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W3165242037
- Cited by
- 285
- References
- 29
- FWCI
- 13.37
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
