The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Activation of Manganese Oxidants with Bisulfite for Enhanced Oxidation of Organic Contaminants: The Involvement of Mn(III)
Abstract
MnO4(-) was activated by HSO3(-), resulting in a process that oxidizes organic contaminants at extraordinarily high rates. The permanganate/bisulfite (PM/BS) process oxidized phenol, ciprofloxacin, and methyl blue at pHini 5.0 with rates (kobs ≈ 60-150 s(-1)) that were 5-6 orders of magnitude faster than those measured for permanganate alone, and ∼5 to 7 orders of magnitude faster than conventional advanced oxidation processes for water treatment. Oxidation of phenol was fastest at pH 4.0, but still effective at pH 7.0, and only slightly slower when performed in tap water. A smaller, but still considerable (∼3 orders of magnitude) increase in oxidation rates of methyl blue was observed with MnO2 activated by HSO3(-) (MO/BS). The above results, time-resolved spectroscopy of manganese species under various conditions, stoichiometric analysis of pH changes, and the effect of pyrophosphate on UV absorbance spectra suggest that the reactive intermediate(s) responsible for the extremely rapid oxidation of organic contaminants in the PM/BS process involve manganese(III) species with minimal stabilization by complexation. The PM/BS process may lead to a new category of advanced oxidation technologies based on contaminant oxidation by reactive manganese(III) species, rather than hydroxyl and sulfate radicals.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Environmental organic chemistry
(1993) · Choice Reviews Online · doi:10.5860/choice.30-6184 · Cited by 1,325
Anipsitakis, G. P., Dionysiou, D. D., & Gonzalez, M. A. (2006) · Environmental Science & Technology · doi:10.1021/es050634b · Cited by 910
An, T., Yang, H., Li, G., Song, W., Cooper, W. J., & Nie, X. (2010) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2009.12.002 · Cited by 649
Reductive Dissolution of Manganese(III/Iv) Oxides by Substituted Phenols
Stone, A. T. (1987) · Environmental Science & Technology · doi:10.1021/es50001a011 · Cited by 523
Evidence for the presence of Mn(III) intermediates in the bacterial oxidation of Mn(II)
Webb, S. M., Dick, G. J., Bargar, J. R., & Tebo, B. M. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0409119102 · Cited by 360
Kinetics of Contaminant Degradation by Permanganate
Waldemer, R. H., & Tratnyek, P. G. (2006) · Environmental Science & Technology · doi:10.1021/es051330s · Cited by 356
Self-citationOxidation of aniline and other primary aromatic amines by manganese dioxide
Laha, S., & Luthy, R. G. (1990) · Environmental Science & Technology · doi:10.1021/es00073a012 · Cited by 334
Free-radical chemistry of sulfite.
Neta, P., & Huie, R. E. (1985) · Environmental Health Perspectives · doi:10.1289/ehp.8564209 · Cited by 312
Xie, P., Ma, J., Fang, J., Guan, Y., Yue, S., Li, X., & Chen, L. (2013) · Environmental Science & Technology · doi:10.1021/es4027024 · Cited by 281
Self-citationGarcia-Segura, S., & Brillas, E. (2011) · Water Research · doi:10.1016/j.watres.2011.03.017 · Cited by 279
Jiang, J., Pang, S.-Y., & Ma, J. (2009) · Environmental Science & Technology · doi:10.1021/es901663d · Cited by 252
Zamora, P. L., & Villamena, F. A. (2012) · The Journal of Physical Chemistry A · doi:10.1021/jp3039169 · Cited by 187
Oxidation Kinetics of Antibiotics during Water Treatment with Potassium Permanganate
Hu, L., Martin, H. M., & Strathmann, T. J. (2010) · Environmental Science & Technology · doi:10.1021/es101331j · Cited by 186
Hu, L., Stemig, A. M., Wammer, K. H., & Strathmann, T. J. (2011) · Environmental Science & Technology · doi:10.1021/es104234m · Cited by 170
Principles and practices of in situ chemical oxidation using permanganate
Siegrist, R. L. (2001) · Battelle Press eBooks · Cited by 158
Optimal methods for quenching H2O2 residuals prior to UFC testing
Liu, W., Andrews, S., Stefan, M. I., & Bolton, J. R. (2003) · Water Research · doi:10.1016/s0043-1354(03)00264-1 · Cited by 143
Reinvestigation of the Role of Humic Acid in the Oxidation of Phenols by Permanganate
Sun, B., Zhang, J., Du, J., Qiao, J., & Guan, X. (2013) · Environmental Science & Technology · doi:10.1021/es404138s · Cited by 133
Self-citationZhang, J., Sun, B., & Guan, X. (2013) · Separation and Purification Technology · doi:10.1016/j.seppur.2013.01.023 · Cited by 128
Self-citationApplication of permanganate in the oxidation of micropollutants: a mini review
Guan, X., He, D., Ma, J., & Chen, G. (2010) · 中国环境科学与工程前沿：英文版 · doi:10.1007/s11783-010-0252-8 · Cited by 120
Self-citationParabola-Like Shaped pH-Rate Profile for Phenols Oxidation by Aqueous Permanganate
Du, J., Sun, B., Zhang, J., & Guan, X. (2012) · Environmental Science & Technology · doi:10.1021/es302076s · Cited by 111
Self-citationLi, L., Shao, C., Lin, T., Shen, J., Yu, S., Shang, R., Yin, D., Zhang, K., & Gao, N. (2014) · Environmental Science & Technology · doi:10.1021/es405014g · Cited by 96
Kinetics and Mechanism of the Oxidation of HSO3- by O2. 2. The Manganese(II)-Catalyzed Reaction
Connick, R. E., & Zhang, Y. (1996) · Inorganic Chemistry · doi:10.1021/ic951141i · Cited by 95
Removal of emerging pollutants by Ru/TiO2-catalyzed permanganate oxidation
Zhang, J., Sun, B., Xiong, X., Gao, N., Song, W., Du, E., Guan, X., & Zhou, G. (2014) · Water Research · doi:10.1016/j.watres.2014.06.028 · Cited by 74
Self-citationCharacteristics and applications of controlled–release KMnO4 for groundwater remediation
Lee, E. S., & Schwartz, F. W. (2006) · Chemosphere · doi:10.1016/j.chemosphere.2006.09.093 · Cited by 72
Ruthenium Nanoparticles Supported on CeO2 for Catalytic Permanganate Oxidation of Butylparaben
Zhang, J., Sun, B., Guan, X., Wang, H., Bao, H., Huang, Y., Qiao, J., & Zhou, G. (2013) · Environmental Science & Technology · doi:10.1021/es402118v · Cited by 69
Self-citationKochany, J., & Lipczyńska‐Kochany, E. (1992) · Chemosphere · doi:10.1016/0045-6535(92)90018-m · Cited by 68
Oxidation of non-steroidal anti-inflammatory drugs with aqueous permanganate
Rodríguez-Álvarez, T., Rodil, R., Quintana, J. B., Triñanes, S., & Cela, R. (2013) · Water Research · doi:10.1016/j.watres.2013.03.034 · Cited by 66
Effect of quenching time and quenching agent dose on total organic halogen measurement
Liu, J., & Zhang, X. (2012) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2012.727807 · Cited by 31
Cited by
Qian, K., Chen, H., Li, W., Ao, Z., Wu, Y.-N., & Guan, X. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c08805 · Cited by 517
Self-citationSulfite-based advanced oxidation and reduction processes for water treatment
Wu, S., Shen, L., Lin, Y., Yin, K., & Yang, C. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.128872 · Cited by 382
Contaminants of emerging concern: a review of new approach in AOP technologies
Salimi, M., Esrafili, A., Gholami, M., Jonidi Jafari, A., Rezaei Kalantary, R., Farzadkia, M., Kermani, M., & Sobhi, H. R. (2017) · Environmental Monitoring and Assessment · doi:10.1007/s10661-017-6097-x · Cited by 313
Metadata
- Authors
- Sun, B., Guan, X., Fang, J., & Tratnyek, P. G.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-09
- Volume
- 49
- Issue
- 20
- Pages
- 12414-12421
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2208083189
- Cited by
- 320
- References
- 29
- FWCI
- 13.34
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
