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A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection
Abstract
A porous luminescent zinc(II) metal-organic framework (MOF) with a NbO net [Zn2(tptc)(apy)2-x(H2O)x]·H2O (1) (where x ≈ 1, apy = aminopyridine, H4tptc = terphenyl-3,3″,5,5″-tetracarboxylic acid), constructed using paddlewheel [Zn2(COO)4] clusters and π-electron-rich terphenyl-tetracarboxylic acid, has been solvothermally synthesized and characterized. Interestingly, the material displays efficient, reversible adsorption of radioactive I2 in vapor and in solution (up to 216 wt %). The strong affinity for I2 is mainly due to it having large porosity, a conjugated π-electron aromatic system, halogen bonds, and electron-donating aminos. Furthermore, luminescent study indicated that 1 exhibits high sensitivity to electron-deficient nitrobenzene explosives via fluorescence quenching.
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Cited by
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Iodine capture in porous organic polymers and metal–organic frameworks materials
Xie, W., Cui, D., Zhang, S.-R., Xu, Y.-H., & Jiang, D.-L. (2019) · Materials Horizons · doi:10.1039/c8mh01656a · Cited by 622
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
An Elastic Hydrogen-Bonded Cross-Linked Organic Framework for Effective Iodine Capture in Water
Lin, Y., Jiang, X., Kim, S. T., Alahakoon, S. B., Hou, X., Zhang, Z., Thompson, C. M., Smaldone, R. A., & Ke, C. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03204 · Cited by 319
Metadata
- Authors
- Yao, R.-X., Cui, X., Jia, X.-X., Zhang, F.-Q., & Zhang, X.-M.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-31
- Volume
- 55
- Issue
- 18
- Pages
- 9270-9275
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2511397570
- Cited by
- 214
- References
- 0
- FWCI
- 9.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Yao, R.-X., Cui, X., Jia, X.-X., Zhang, F.-Q., & Zhang, X.-M. (2016). A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.6b01312
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